TMPTMA Monomer / Trimethylolpropane trimethacrylate CAS 3290-92-4

(1 customer review)

Chemical Name: Trimethylolpropane trimethacrylate

Other Name: TMPTMA; ACRYESTER TMP;MIRAMER M301;Trimethacrylate de propylidynetrimethyle ;Trimetacrilato de propilidintrimetilo;2,2-bis[(methacryloyloxy)methyl]butyl methacrylate (non-preferred name)

CAS No.: 3290-92-4

Molecular Fomula:338.39544

Molecular weight: 246.43

Chemical Structure:Trimethylolpropane trimethacrylate Structure

Appearance:colorless clear liquid

Assay: 98%

Description

TMPTMA Monomer / Trimethylolpropane trimethacrylate CAS 3290-92-4

Appearance

colorless clear liquid

Assay

99.5%min

Isomer

0.1%max

Free acid

0.2%max

This product can replace Trimethylolpropane trimethacrylate; ACRYESTER TMP;MIRAMER M301;Trimethacrylate de propylidynetrimethyle ;Trimetacrilato de propilidintrimetilo;2,2-bis[(methacryloyloxy)methyl]butyl methacrylate (non-preferred name).

Trimethylolpropane trimethacrylate Usage

1. Trimethylolpropane trimethacrylate can be used as a cross-linking agent for peroxide cross-linking. It is suitable for mixing POLYBUTADIENE DIACRYLATE, POLY(PROPYLENE-CO-ETHYLENE), EPDM RUBBER, Isoprene rubber, acrylonitrile-butadiene rubber.

2. Trimethylolpropane trimethacrylate can be used as a vulcanizing agent. When synthetic rubber is vulcanized with peroxide, TMPTMA can improve corrosion resistance, aging resistance and hardness, heat resistance. TMPTMA plasticizes during mixing and vulcanizes the original Hardening effect, can be used for NBR, EPDM, acrylic rubber.

3. Trimethylolpropane trimethacrylate can be used as a cross-linking agent. TMPTMA can reduce radiation dose, shorten radiation time, increase cross-linking density, and has the characteristics of low precision, high cross-linking degree, low vapor pressure and fast curing speed. It can be used for light-curing inks and light. Polymeric materials.

4. PVC is blended into the car body sealing agent, caulking agent and all the PVC solution molding.

5. Special rubber’s vulcanization-assisting activator, ethylene propylene propylene rafter rubber and EPDM rubber, chloro rubber, silicone rubber, polyurethane, ethylene/vinyl acetate copolymer (EVA), chlorinated polyethylene elastomer (CPE) and other special rubbers Vulcanization is very difficult, and organic peroxides (such as DCP, BPO) are generally used for vulcanization. If a single organic peroxide is used for vulcanization, the vulcanization time is too long and the vulcanization is insufficient, and it is difficult to ensure good mechanical and physical properties. Therefore, TMPTMA must be added as a vulcanizing agent to achieve good results.

6. For example, organic fluorine rubber, etc., when using DCP for vulcanization, if the additive 1~4% TMPTMA is used as a vulcanizing agent, it can not only greatly shorten the vulcanization time, increase the degree of vulcanization, and reduce the amount of DCP, but also significantly improve the machinery of the product. Strength, wear resistance, solvent resistance and corrosion resistance etc. In the vulcanization process of fluorine-containing rubber, the double bond in the TMPTMA molecule not only participates in the vulcanization cross-linking reaction, but also acts as a hydrogen halide (HF, HCL, etc.) acceptor, absorbing the hydrogen halide released during processing, thereby It not only improves the product quality, but also greatly reduces the corrosiveness of the vulcanized rubber. The rubber compound containing TMPTMA has a plasticizing effect during mixing and a hardening effect after vulcanization.

 

Trimethylolpropane trimethacrylate Packaging and Shipping

Packing: 1/kg; 200kg/drum

Delivery: by sea, air and DHL

 

Trimethylolpropane trimethacrylate Storage

Store at low temperature and avoid light.

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Polythiol/Polymercaptan
DMES Monomer Bis(2-mercaptoethyl) sulfide 3570-55-6
DMPT Monomer THIOCURE DMPT 131538-00-6
PETMP Monomer 7575-23-7
PM839 Monomer Polyoxy(methyl-1,2-ethanediyl) 72244-98-5
Monofunctional Monomer
HEMA Monomer 2-hydroxyethyl methacrylate 868-77-9
HPMA Monomer 2-Hydroxypropyl methacrylate 27813-02-1
THFA Monomer Tetrahydrofurfuryl acrylate 2399-48-6
HDCPA Monomer Hydrogenated dicyclopentenyl acrylate 79637-74-4
DCPMA Monomer Dihydrodicyclopentadienyl methacrylate 30798-39-1
DCPA Monomer Dihydrodicyclopentadienyl Acrylate 12542-30-2
DCPEMA Monomer Dicyclopentenyloxyethyl Methacrylate 68586-19-6
DCPEOA Monomer Dicyclopentenyloxyethyl Acrylate 65983-31-5
NP-4EA Monomer (4) ethoxylated nonylphenol 50974-47-5
LA Monomer Lauryl acrylate / Dodecyl acrylate 2156-97-0
THFMA Monomer Tetrahydrofurfuryl methacrylate 2455-24-5
PHEA Monomer 2-PHENOXYETHYL ACRYLATE 48145-04-6
LMA Monomer Lauryl methacrylate 142-90-5
IDA Monomer Isodecyl acrylate 1330-61-6
IBOMA Monomer Isobornyl methacrylate 7534-94-3
IBOA Monomer Isobornyl acrylate 5888-33-5
EOEOEA Monomer 2-(2-Ethoxyethoxy)ethyl acrylate 7328-17-8
Multifunctional monomer
DPHA Monomer 29570-58-9
DI-TMPTA Monomer DI(TRIMETHYLOLPROPANE) TETRAACRYLATE 94108-97-1
Acrylamide monomer
ACMO Monomer 4-acryloylmorpholine 5117-12-4
Di-functional Monomer
PEGDMA Monomer Poly(ethylene glycol) dimethacrylate 25852-47-5
TPGDA Monomer Tripropylene glycol diacrylate 42978-66-5
TEGDMA Monomer Triethylene glycol dimethacrylate 109-16-0
PO2-NPGDA Monomer Propoxylate neopentylene glycol diacrylate 84170-74-1
PEGDA Monomer Polyethylene Glycol Diacrylate 26570-48-9
PDDA Monomer Phthalate diethylene glycol diacrylate
NPGDA Monomer Neopentyl glycol diacrylate 2223-82-7
HDDA Monomer Hexamethylene Diacrylate 13048-33-4
EO4-BPADA Monomer ETHOXYLATED (4) BISPHENOL A DIACRYLATE 64401-02-1
EO10-BPADA Monomer ETHOXYLATED (10) BISPHENOL A DIACRYLATE 64401-02-1
EGDMA Monomer Ethylene glycol dimethacrylate 97-90-5
DPGDA Monomer Dipropylene Glycol Dienoate 57472-68-1
Bis-GMA Monomer Bisphenol A Glycidyl Methacrylate 1565-94-2
Trifunctional Monomer
TMPTMA Monomer Trimethylolpropane trimethacrylate 3290-92-4
TMPTA Monomer Trimethylolpropane triacrylate 15625-89-5
PETA Monomer 3524-68-3
GPTA ( G3POTA ) Monomer GLYCERYL PROPOXY TRIACRYLATE 52408-84-1
EO3-TMPTA Monomer Ethoxylated trimethylolpropane triacrylate 28961-43-5
Photoresist Monomer
IPAMA Monomer 2-isopropyl-2-adamantyl methacrylate 297156-50-4
ECPMA Monomer 1-Ethylcyclopentyl Methacrylate 266308-58-1
ADAMA Monomer 1-Adamantyl Methacrylate 16887-36-8
Methacrylates monomer
TBAEMA Monomer 2-(Tert-butylamino)ethyl methacrylate 3775-90-4
NBMA Monomer n-Butyl methacrylate 97-88-1
MEMA Monomer 2-Methoxyethyl Methacrylate 6976-93-8
i-BMA Monomer Isobutyl methacrylate 97-86-9
EHMA Monomer 2-Ethylhexyl methacrylate 688-84-6
EGDMP Monomer Ethylene glycol Bis(3-mercaptopropionate) 22504-50-3
EEMA Monomer 2-ethoxyethyl 2-methylprop-2-enoate 2370-63-0
DMAEMA Monomer N,M-Dimethylaminoethyl methacrylate 2867-47-2
DEAM Monomer Diethylaminoethyl methacrylate 105-16-8
CHMA Monomer Cyclohexyl methacrylate 101-43-9
BZMA Monomer Benzyl methacrylate 2495-37-6
BDDMP Monomer 1,4-Butanediol Di(3-mercaptopropionate) 92140-97-1
BDDMA Monomer 1,4-Butanedioldimethacrylate 2082-81-7
AMA Monomer Allyl methacrylate 96-05-9
AAEM Monomer Acetylacetoxyethyl methacrylate 21282-97-3
Acrylates Monomer
IBA Monomer Isobutyl acrylate 106-63-8
EMA Monomer Ethyl methacrylate 97-63-2
DMAEA Monomer Dimethylaminoethyl acrylate 2439-35-2
DEAEA Monomer 2-(diethylamino)ethyl prop-2-enoate 2426-54-2
CHA Monomer cyclohexyl prop-2-enoate 3066-71-5
BZA Monomer benzyl prop-2-enoate 2495-35-4

 

The importance of the glass transition temperature (Tg) of acrylic resins, which are commonly used in coating formulations, is briefly described as an example

The glass transition temperature (Tg) is the lowest temperature at which the polymer chain segments can move, and is directly related to the flexibility of the molecular chains. For acrylic resins commonly used in coating formulations, the film becomes soft above its glass transition temperature, so they are usually used below the glass transition temperature, so we also want to use acrylic resins with a higher glass transition temperature. The glass transition temperature (Tg) of acrylic resins is a very important technical indicator, which must be designed and selected correctly, and its importance is mainly expressed in the following aspects. One, the engineer in the design of paint formulations with acrylic resin, once the coating species, performance and other comprehensive requirements to determine the glass transition temperature of acrylic resin Tg, basically also determines the choice of synthetic resin monomer, but also basically determines the performance of acrylic resin and paint after the performance of the paint. The higher the Tg value of the acrylic resin, the better the solvent and corrosion resistance of the coating film; conversely, the lower the Tg value of the resin, the worse the corrosion and solvent resistance of the coating film. Therefore, among the many technical indicators of acrylic resins, the Tg value has a greater impact on the resin and the performance of the coating film. Second, under the same acrylic resin synthesis reaction conditions, the higher the Tg of the resin, the greater the final viscosity of the resin reaction, that is, the higher the average molecular weight; conversely, the lower the Tg of the resin, the lower the final viscosity of the resin reaction, that is, the lower the average molecular weight. The higher the Tg value, the harder the film and the stronger the scratch resistance, but care should be taken to adjust the paint formulation and not to make the film brittle; conversely, the lower the Tg value, the lower the film hardness and the worse the scratch resistance. We often encounter high temperatures in summer when the film is easy to become soft, back to sticky, easy to be contaminated phenomenon, which is the film-forming resin Tg high or low impact on the film hardness and scratch resistance of the visual performance. Fourth, the higher the Tg of the acrylic resin, the better the solvent release of the coating, the better the dry rate of the film after painting; conversely, the worse the solvent release, the worse the dry rate of the film after painting the resin.

1 review for TMPTMA Monomer / Trimethylolpropane trimethacrylate CAS 3290-92-4

  1. Liam Carter

    Swift delivery, exceptional quality. Couldn’t ask for more! Highly satisfied with my purchase.

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