CHLUMICRYL® TMPTA Monomer / Trimethylolpropane triacrylate CAS 15625-89-5

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Chemical Name: Trimethylolpropane triacrylate / TMPTA

Other Name: LAROMER TMPTA; tmpta monomer; Trimethylolpropane triacrylate; 2,2-bis(acryloyloxymethyl)butyl acrylate; 2; ,2-bis(acryloyloxymethyl)butyl acrylate; trimethylolpropane triacrylate; 2-ethyl-2-[[(1-oxoallyl)oxy]methyl]-1,3-propanediyl diacrylate; Acrylic acid, triester with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol; MFM; NK Ester A TMPT; Ogumont T 200; Saret 351; Sartomer SR 351; Setalux UV 2241; SR 351; Trimethylolpropane triacrylate.

CAS No.: 15625-89-5

TMPTA Fomula:C15H20O6

Appearance: Light yellow transparent liquid

Purity: 98.00%

Molecular weight: 296.32

Capacity: 3000tons/year

TMPTA Monomer Tg,℃:62

Packaging: 200kgs/drum

tmpta viscosity: 70-135CPS

tmpta boiling point: 758.19°C at 760 mmHg

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Description

TMPTA Monomer / Trimethylolpropane triacrylate CAS 15625-89-5

 

Item

Specifications

Results

Appearance

Light yellow transparent liquid

Conforms

Solid content (wt%)

≥98.00%

99.65%

Acid value (mgkoh/g)

≤1.00

0.40

Viscosity (cps25 degree)

80~120

120

Color (Pt-Co)

≤60

30

Conclusion

The results conforms with Enterprise standards

 

What is TMPTA Monomer?

1. TMPTA belongs to polyol acrylate, which is an important multifunctional monomer with high activity. The trimethyl propylene dilute acid ester has high molecular double bond content and fast curing speed. It is an excellent crosslinking agent and curing agent. Due to the high boiling point of Trimethylolpropane triacrylate, there is no solvent volatilization during the curing process. It is not only environmentally friendly, but also highly energy-saving. Therefore, it is widely used in many fields such as coatings, adhesives, inks, electronics, and rubber. The synthesis of trimethyl propylene triacrylate is of great significance.

2. TMPTA is a newly developed variety in the acrylic series products, and is an important trifunctional acrylate functional monomer. Because TMPTA has the characteristics of high double bond content, fast curing speed, low viscosity, high boiling point, low volatility, etc., it has become the most widely used and the largest amount of multifunctional acrylic reactive crosslinking diluent in the field of radiation curing. At present, TMPTA is mainly synthesized by the direct esterification of trimethylpropane (TM) P and acrylic acid (AA) or the transesterification of TMP with methyl acrylate (MA). Most of the catalysts used in this process are sulfuric acid or p-toluenesulfonic acid. [‘Several due to equipment corrosion and complex processes such as neutralization and water washing during post-treatment, the product cost is relatively high. The author uses trimethylpropane and acrylic acid as raw materials, sulfuric acid as a catalyst, cyclohexane and toluene as a water-carrying agent, and a mixed system of hydroquinone and phenoin as a polymerization inhibitor to synthesize TMPTA, which has achieved good results.

3. TMPTA Monomer is a versatile monomer with a wide range of industrial applications as a crosslinker, reactive diluent and chemical intermediate.TMPTA Monomer is used in the production of UV-curable inks, electron beam irradiation-curable coatings, thermal papers, plastic hardeners, optical fibers, UV-curable acrylic varnishes for the furniture industry, polymers and resins; TMPTA Monomer is used as a component of photopolymers and flexographic printing plates and photoresists; and as a component of acrylic glues, adhesives and anaerobic sealants.

This product can replace 2,2-bis(acryloyloxymethyl)butyl acrylate; 2; ,2-bis(acryloyloxymethyl)butyl acrylate; trimethylolpropane triacrylate; 2-ethyl-2-[[(1-oxoallyl)oxy]methyl]-1,3-propanediyl diacrylate; Acrylic acid, triester with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol; MFM; NK Ester A TMPT; Ogumont T 200; Saret 351; Sartomer SR 351; Setalux UV 2241; SR 351; Trimethylolpropane triacrylate.

Product features

high solid content, low viscosity, low solvent residue, good color, almost no low polymer, low moisture, low acid value, low polymerization inhibitor content

 

Trimethylolpropane triacrylate Usage

1. TMPTA Monomer (TRIMETHYLOLPROPANE TRIACRYLATE) is a widely used reactive diluent in ultraviolet light (UV) and electron beam (EB) curable coatings and inks.

2. TMPTA Monomer can be used as a vulcanization activator for special rubber. Special rubbers such as ethylene propylene rafter rubber and EPDM rubber, chloro rubber, silicone rubber, polyurethane, ethylene/vinyl acetate copolymer (EVA), chlorinated polyethylene elastomer (CPE), etc. are difficult to vulcanize, and organic Peroxide (such as DCP, BPO) is vulcanized. If a single organic peroxide is used for vulcanization, the vulcanization time is too long and the vulcanization is insufficient, and it is difficult to ensure good mechanical and physical properties. Therefore, TMPTMA must be added as a vulcanizing aid to achieve good results.

3. For example, organic fluorine rubber, etc., when using DCP for vulcanization, if the additive 1~4% TMPTMA is used as a vulcanizing agent, it can not only greatly shorten the vulcanization time, increase the degree of vulcanization, reduce the amount of DCP, but also significantly improve the mechanical Strength, wear resistance, solvent resistance and corrosion resistance etc.

4. In the vulcanization process of fluorine-containing rubber, the double bond in the TMPTMA molecule not only participates in the vulcanization cross-linking reaction, but also acts as a hydrogen halide (HF, HCL, etc.) acceptor to absorb the hydrogen halide released during processing , Which not only improves the quality of products, but also greatly reduces the corrosivity of vulcanized rubber. The rubber compound containing TMPTMA has a plasticizing effect during mixing and a hardening effect after vulcanization.

 

Trimethylolpropane triacrylate Packaging

25kg; 200kgs/drum.

Temperature: 0℃-30℃, storage period is 12 months.

 

Measured Atlas

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Polythiol/Polymercaptan
DMES Monomer Bis(2-mercaptoethyl) sulfide 3570-55-6
DMPT Monomer THIOCURE DMPT 131538-00-6
PETMP Monomer 7575-23-7
PM839 Monomer Polyoxy(methyl-1,2-ethanediyl) 72244-98-5
Monofunctional Monomer
HEMA Monomer 2-hydroxyethyl methacrylate 868-77-9
HPMA Monomer 2-Hydroxypropyl methacrylate 27813-02-1
THFA Monomer Tetrahydrofurfuryl acrylate 2399-48-6
HDCPA Monomer Hydrogenated dicyclopentenyl acrylate 79637-74-4
DCPMA Monomer Dihydrodicyclopentadienyl methacrylate 30798-39-1
DCPA Monomer Dihydrodicyclopentadienyl Acrylate 12542-30-2
DCPEMA Monomer Dicyclopentenyloxyethyl Methacrylate 68586-19-6
DCPEOA Monomer Dicyclopentenyloxyethyl Acrylate 65983-31-5
NP-4EA Monomer (4) ethoxylated nonylphenol 50974-47-5
LA Monomer Lauryl acrylate / Dodecyl acrylate 2156-97-0
THFMA Monomer Tetrahydrofurfuryl methacrylate 2455-24-5
PHEA Monomer 2-PHENOXYETHYL ACRYLATE 48145-04-6
LMA Monomer Lauryl methacrylate 142-90-5
IDA Monomer Isodecyl acrylate 1330-61-6
IBOMA Monomer Isobornyl methacrylate 7534-94-3
IBOA Monomer Isobornyl acrylate 5888-33-5
EOEOEA Monomer 2-(2-Ethoxyethoxy)ethyl acrylate 7328-17-8
Multifunctional monomer
DPHA Monomer 29570-58-9
DI-TMPTA Monomer DI(TRIMETHYLOLPROPANE) TETRAACRYLATE 94108-97-1
Acrylamide monomer
ACMO Monomer 4-acryloylmorpholine 5117-12-4
Di-functional Monomer
PEGDMA Monomer Poly(ethylene glycol) dimethacrylate 25852-47-5
TPGDA Monomer Tripropylene glycol diacrylate 42978-66-5
TEGDMA Monomer Triethylene glycol dimethacrylate 109-16-0
PO2-NPGDA Monomer Propoxylate neopentylene glycol diacrylate 84170-74-1
PEGDA Monomer Polyethylene Glycol Diacrylate 26570-48-9
PDDA Monomer Phthalate diethylene glycol diacrylate
NPGDA Monomer Neopentyl glycol diacrylate 2223-82-7
HDDA Monomer Hexamethylene Diacrylate 13048-33-4
EO4-BPADA Monomer ETHOXYLATED (4) BISPHENOL A DIACRYLATE 64401-02-1
EO10-BPADA Monomer ETHOXYLATED (10) BISPHENOL A DIACRYLATE 64401-02-1
EGDMA Monomer Ethylene glycol dimethacrylate 97-90-5
DPGDA Monomer Dipropylene Glycol Dienoate 57472-68-1
Bis-GMA Monomer Bisphenol A Glycidyl Methacrylate 1565-94-2
Trifunctional Monomer
TMPTMA Monomer Trimethylolpropane trimethacrylate 3290-92-4
TMPTA Monomer Trimethylolpropane triacrylate 15625-89-5
PETA Monomer 3524-68-3
GPTA ( G3POTA ) Monomer GLYCERYL PROPOXY TRIACRYLATE 52408-84-1
EO3-TMPTA Monomer Ethoxylated trimethylolpropane triacrylate 28961-43-5
Photoresist Monomer
IPAMA Monomer 2-isopropyl-2-adamantyl methacrylate 297156-50-4
ECPMA Monomer 1-Ethylcyclopentyl Methacrylate 266308-58-1
ADAMA Monomer 1-Adamantyl Methacrylate 16887-36-8
Methacrylates monomer
TBAEMA Monomer 2-(Tert-butylamino)ethyl methacrylate 3775-90-4
NBMA Monomer n-Butyl methacrylate 97-88-1
MEMA Monomer 2-Methoxyethyl Methacrylate 6976-93-8
i-BMA Monomer Isobutyl methacrylate 97-86-9
EHMA Monomer 2-Ethylhexyl methacrylate 688-84-6
EGDMP Monomer Ethylene glycol Bis(3-mercaptopropionate) 22504-50-3
EEMA Monomer 2-ethoxyethyl 2-methylprop-2-enoate 2370-63-0
DMAEMA Monomer N,M-Dimethylaminoethyl methacrylate 2867-47-2
DEAM Monomer Diethylaminoethyl methacrylate 105-16-8
CHMA Monomer Cyclohexyl methacrylate 101-43-9
BZMA Monomer Benzyl methacrylate 2495-37-6
BDDMP Monomer 1,4-Butanediol Di(3-mercaptopropionate) 92140-97-1
BDDMA Monomer 1,4-Butanedioldimethacrylate 2082-81-7
AMA Monomer Allyl methacrylate 96-05-9
AAEM Monomer Acetylacetoxyethyl methacrylate 21282-97-3
Acrylates Monomer
IBA Monomer Isobutyl acrylate 106-63-8
EMA Monomer Ethyl methacrylate 97-63-2
DMAEA Monomer Dimethylaminoethyl acrylate 2439-35-2
DEAEA Monomer 2-(diethylamino)ethyl prop-2-enoate 2426-54-2
CHA Monomer cyclohexyl prop-2-enoate 3066-71-5
BZA Monomer benzyl prop-2-enoate 2495-35-4

 

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