CHLUMINIT® OXE-02 / Photoinitiator OXE-02 CAS 478556-66-0

CHLUMINIT® OXE-02 is an oxime ester photoinitiator with high photosensitivity and a broad absorption peak, used to initiate the free radical polymerization of ethylenically unsaturated monomers or multifunctional vinyl monomers. Especially suitable for applications requiring extremely high photosensitivity and low yellowing. Mainly used as spacer materials for displays, microlens materials, covering layers and dielectric or insulating layers and is a low in toxicity, odor, and environmentally friendly photoinitiator.

Description

Photoinitiator OXE-02

Synonym:  1-(O-Acetyloxime)-1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]ethanone; CHLUMINIT® OXE-02; Irgacure OXE-02

CAS No:  478556-66-0

Molecular Formula:C26H24N2O3

LED 375nm

General Information:

OXE-02 is an oxime ester photoinitiator with high photosensitivity and a broad absorption peak. OXE-02 can be used in conjunction with LEDs. OXE-02 can be used in both colorless and colored systems and is low in toxicity, odor, and environmentally friendly.

Specification:

Appearance White to light yellow powder
Purity ≥99%
Absorption peak 295/368/380/400
Volatile content ≤0.5%
Melting point 122-129°C

CHLUMINIT® OXE-02 Usage:

From architectural decoration to electronic equipment manufacturing, from everyday printed matter to the production of high-end precision instruments, materials such as UV coatings, UV inks and UV adhesives all play an indispensable role. The application of the photoinitiator OXE-02 in these materials is extensive and significant. Take UV coatings, for example. In the coating of building facades, these coatings not only dry quickly, but also have excellent weather resistance. The photoinitiator OXE-02 plays a key role in initiating the polymerization reaction, which causes the coating to cure quickly and form a strong and beautiful coating. Similarly, UV inks used in the manufacture of electronic devices require high-precision printing results. Photoinitiator OXE-02 ensures that the ink cures precisely under UV light, ensuring the clarity and durability of the printed pattern.

It is also worth mentioning that it also performs excellently in the field of UV adhesives. For example, in the assembly of automotive parts, a fast-curing and high-strength adhesive is required, and UV adhesives are the first choice. The photoinitiator OXE-02 is the core factor that allows this adhesive to perform its powerful function. In addition, it also plays an irreplaceable role in preservatives and fluxes. In the corrosion protection of metal products that are exposed to harsh environments for long periods of time, corrosion inhibitors containing photoinitiator OXE-02 can form a dense protective film to effectively prevent the metal from being eroded by the external environment.

In actual use, there are strict requirements for the amount of photoinitiator OXE-02 used. According to a large amount of experimental data and industrial practice, the recommended dosage is 0.5–5% (w/w). This dosage range is not set arbitrarily, but is the result of repeated testing. When the dosage is lower than 0.5%, the polymerization reaction may not be initiated effectively, resulting in substandard product performance. For example, UV coatings may not dry completely, resulting in poor adhesion. When the dosage exceeds 5%, not only will the cost increase, but some negative effects may also occur. For example, excessive polymerization may make the product brittle, affecting its flexibility and durability.

this dosage range is also affected by other factors in different application scenarios, such as the intensity of UV light, irradiation time, ambient temperature, etc. Assuming that UV coating is applied in a high-temperature environment, due to the effect of temperature on the reaction rate, the dosage of photoinitiator OXE-02 may need to be slightly adjusted by reducing the dosage appropriately to avoid quality problems caused by excessive reaction. On the contrary, in a low-temperature environment or when the UV light intensity is weak, the dosage may need to be slightly increased to ensure the reaction proceeds normally. These are all complex factors that need to be considered in the actual production process, which further highlights the importance of accurately controlling the dosage of photoinitiator OXE-02.

 

Package:

1kg/Bag

Storage:

Stored in a cool dry place out of direct sunlight.

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OXE-02 is a highly efficient radical-type photoinitiator belonging to the alkoxyphosphine family. Its key characteristics include long absorption wavelength, high photolysis efficiency, and rapid curing speed, coupled with outstanding deep-curing and yellowing resistance. This makes it particularly suitable for applications demanding high curing thickness, fast curing speed, and color stability.

1. UV-LED Curing Systems

This represents OXE-02's most significant and fastest-growing application segment.
  • Reason: Traditional mercury lamps emit broad-spectrum UV radiation, whereas UV-LED light sources emit monochromatic light at specific wavelengths (typically 365nm, 385nm, 395nm, or 405nm). OXE-02 exhibits strong absorption in the long-wave UVA region (particularly 350-420nm), perfectly matching the emission wavelengths of mainstream UV-LED light sources.
  • Application Products:
    • UV-LED Inks (e.g., inkjet printing, flexographic printing)
    • UV-LED Coatings
    • UV-LED Adhesives

2. White and Colored Systems

OXE-02 is a critical component in white coating and ink formulations.
  • Reason: White pigments like titanium dioxide strongly scatter and block short-wave UV light, preventing penetration into deeper coating layers. OXE-02's long-wave absorption properties enable it to penetrate the pigment barrier, effectively initiating curing at the coating base. This prevents “surface dry, base wet” issues and ensures excellent adhesion.
  • Application Products:
    • UV topcoats for white goods (e.g., refrigerators, washing machines)
    • White printing inks for paper and plastics
    • Colored paint systems containing other high-opacity pigments

3. Thick Coatings and Composites

OXE-02 is ideal for applications requiring single-pass curing of thick coatings.
  • Reason: Long-wave UV light penetrates deeper than short-wave UV. OXE-02 effectively absorbs this long-wave energy, ensuring uniform photopolymerization throughout the coating thickness for complete curing.
  • Application Products:
    • Wood filler putty
    • Electronic Component Encapsulation Adhesives
    • Glass Fiber Reinforced Composites (e.g., FRP)

4. Applications Requiring Yellowing Resistance

Compared to some traditional initiators (e.g., ITX), OXE-02 and its photolysis products exhibit lighter coloration, thereby better preserving the original hue of cured materials.
  • Reason: Its molecular structure and photolysis products are less prone to generating chromophores.
  • Application Products:
    • High-transparency varnishes and topcoats
    • Overprint varnishes requiring high color fidelity
    • Plastic coatings demanding high color stability (e.g., PET, PMMA)

5. 3D Printing (UV Curing)

In UV-curing 3D printing, OXE-02 serves as a critical photoinitiator.
  • Reason: Many desktop and industrial LCD/DLP 3D printers utilize 405nm UV-LEDs as light sources. OXE-02 exhibits high compatibility with this wavelength, ensuring rapid and precise resin curing with superior dimensional accuracy.
  • Application Products:
    • LCD (mask exposure) and DLP (digital light processing) 3D printing photopolymer resins.

Key Advantages Summary

  1. Long-Wavelength Absorption: Perfectly matches UV-LED light sources (365-405nm).
  2. Deep Curing Capability: Effectively cures white, high-opacity pigment systems and thick coatings.
  3. Low Yellowing: Yields color-pure cured products with superior aging resistance.
  4. High Photolysis Efficiency: As a Type I initiator, it directly decomposes into active radicals upon photon absorption without requiring co-initiators, enabling rapid curing.
  5. Excellent Compatibility: Compatible with most acrylic oligomers and monomers.
In summary, OXE-02 is a high-performance, indispensable photoinitiator in modern UV curing technology, particularly UV-LED curing systems, widely applied in premium printing, coatings, adhesives, and emerging 3D printing applications.

Additional information

Chemical Name

Photoinitiator OXE-02

CAS No.

478556-66-0

Molecular Formula

C26H24N2O3

Assay

99%min

Package

1kg/bag,10kgs/carton

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