First, the causes and solutions of plastic yellowing.
The effective solution to plastic yellowing is to add antioxidants, ultraviolet absorbers, light stabilizers, etc., which can effectively prevent and delay the occurrence of yellowing. However, there are many kinds of antioxidants, from which the selection of suitable products requires certain technical support and experience.
The important culprit causing oxidative yellowing of plastics and ultraviolet rays, the source is mainly sunlight, therefore, especially in the face of the production of products need to be used outdoors customers, will add a certain amount of ultraviolet absorber, light stabilizers, etc., to delay yellowing.
Second, what is the difference between the classification of antioxidants and the mechanism?
One is the main antioxidant: capture peroxide radicals, mainly hindered phenolic antioxidants; the main anti-space hindered phenols, antioxidants 1010, antioxidants 1076 that belong to this category, through the capture of free radicals generated in the process of degradation of plastics and the long-term continuity of the role of antioxidant.
One kind of auxiliary antioxidant: decomposition of hydroperoxides, mainly phosphite esters, thioesters. Auxiliary antioxidants – phosphite and thioesters, 168 belongs to the phosphite auxiliary antioxidants, through the decomposition of plastic further degradation of peroxides generated to achieve the purpose of antioxidant, mainly to provide heat processing stability; the main antioxidant + auxiliary antioxidants can be used together to produce synergistic effects (a simple analogy: 1 + 1 > 2).
According to the chemical structure, 1010,1076 belongs to hindered phenol, 168 belongs to phosphite.
According to the mechanism of action, 1010,1076 belongs to capture free radicals and 168 belongs to decompose hydroperoxides.
The first two are the main antioxidants, 168 is an auxiliary antioxidant, the main antioxidant is to focus on the product’s long-term anti-aging, auxiliary antioxidants are generally stabilized in the process!
In general, according to each manufacturer’s production process and raw materials, solvents, additives, fillers, which stage of yellowing, yellowing degree of difference, and recommended the use of different antioxidants.
Third, antioxidant 1010, antioxidant 1076, 168 basic physical data
Antioxidant 1010
Antioxidant 1010 is white crystalline powder with stable chemical properties, which can be widely used in general plastics, engineering plastics, synthetic rubber, fibers, hot melt adhesives, resins, oils, inks, coatings and other industries.
Basic information
Common name: Antioxidant 1010.
Chemical name: Tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid] pentaerythritol ester.
Properties: white crystalline powder; soluble in benzene, acetone, chloroform, slightly soluble in ethanol, insoluble in water.
Storage and transportation: the chemical properties of this product is stable, no special storage requirements, should be moisture-proof, heat insulation.
Structural formula:
Common quality index: melting point 110.0～125.0℃, content ≥98.0%, density 1.15, transmittance (10g/100mL toluene) ≥95% (425nm), ≥97% (500nm), volatility ≤0.5%, ash ≤0.1%, chromaticity (10g/100mL toluene) (APHA) ≤50.
Toxicity and hygiene: The toxicity of this product is very low, rat oral LD50>5g/kg, can be used in food packaging materials.
CAS No.: 6683-19-8
2 Basic characteristics
(1) Antioxidant 1010 is a phenolic antioxidant, which is one of the excellent varieties of antioxidants at present.
(2) Antioxidant 1010 has excellent antioxidant performance for polypropylene and polyethylene. It can effectively extend the service life of the products.
(3) Antioxidant 1010 has small volatility, good extraction resistance, high thermal stability, long lasting effect, no coloring, no pollution, .
(4) Antioxidant 1010 and antioxidant DLTP, 168 and have a synergistic effect.
(5) Antioxidant 1010 is a high molecular weight hindered phenol antioxidant, with low volatility, and not easy to migrate, resistant to extraction.
(6) Antioxidant 1010 can effectively prevent thermo-oxidative degradation of polymer materials during long-term aging, and is also an efficient processing stabilizer that improves the discoloration resistance of polymer materials under high-temperature processing conditions.
(7) Antioxidant 1010 is used in the field of polyurethane, it can be used in RIM materials, spandex, TPU, adhesives and sealants. It is widely used in olefin resins, such as polyethylene, polypropylene, polyurethane, polyformaldehyde, ABS resin, polyvinyl acetal, synthetic rubber and petroleum products, and the general dosage is 0.1% to 0.5%.
Application areas of antioxidant 1010
It can be widely used in general plastics, engineering plastics, synthetic rubber, fibers, hot melt adhesives, resins, oils, inks, coatings and other industries.
Antioxidant 1010 is a poly hindered phenolic antioxidant with good compatibility with most polymers. Antioxidant 1010 has good protection against light and heat induced discoloration. It is widely used in PE, PP, PS, polyamide, polyformaldehyde, ABS resin, PVC, synthetic rubber and other polymer materials. Also used to prevent grease and paint thermal oxygen aging.
V. What is the difference between Antioxidant 1010 and Antioxidant 1076?
Both are hindered phenolic antioxidants, but the effective functional group of 1010 is four times more than that of antioxidant 1076, which means that it is more effective. The main considerations for usage are compatibility with the resin at a later stage and processing conditions.
Properties of antioxidant 1010: white crystalline powder. Melting point 119～122℃. No change, no pollution, heat aging resistance, water washing resistance, non-volatile. Widely used in thermal processing of polypropylene, polyethylene, polyformaldehyde, ABS resin and so on. It can prolong the service life of plastic products. It is synthesized from 4-hydroxy-3,5-tert-butylphenylpropionic acid methyl ester made from phenol and then synthesized with pentaerythritol in the presence of sodium methanol catalyst.
Antioxidant 1076 Properties: white crystalline powder. Odorless . Melting point 50～55℃. No pollution, no color change, small volatility, good thermal stability. Good mutual solubility with most polymers. Insoluble in water, soluble in many organic solvents. Used in polypropylene, polyethylene, polystyrene, polyvinyl chloride, ABS resin, polyamide, polyester and so on. It is produced by the action of phenol and isobutylene to form 3,5-di-tert-butyl-4-hydroxybenzenepropanoic acid, and then esterified with octadecanol.
Next Post: Antioxidant 1076: Elevate Your Products with Superior Stability and Brilliance
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| Formulation Products | ||
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| CHLUMIAO® 1425 | CAS 65140-91-2 | Irganox 1425 / Dragonox 1425 / Antioxidant 1425 / BNX 1425 |
| CHLUMIAO® 1726 | CAS 110675-26-8 | Antioxidant 1726 / Irganox 1726 / Omnistab AN 1726 |
| CHLUMIAO® 3052 | CAS 61167-58-6 | IRGANOX 3052 / 4-methylphenyl Acrylate / Antioxidant 3052 |
| CHLUMIAO® 5057 | CAS 68411-46-1 | Irganox 5057 / Antioxidant 5057 / Omnistab AN 5057 |
| CHLUMIAO® 697 | CAS 70331-94-1 | Antioxidant 697 / Irganox 697 / Naugard XL-1 / Antioxidant 697 |
| CHLUMIAO® 80 | CAS 90498-90-1 | Irganox 80 / Antioxidant 80 |
| CHLUMIAO® 1024 | CAS 32687-78-8 | Irganox 1024 / Antioxidant 1024 |
| CHLUMIAO® 1035 | CAS 41484-35-9 | Irganox 1035 / Antioxidant 1035 |
| CHLUMIAO® HE-S01/N40 | ||
| CHLUMIAO® HN-55/70/80/502/510/514/516/602 | ||
| CHLUMIAO® HC-30/100 | ||
| CHLUMIAO® HO-17/17EH | ||
| CHLUMIAO® HS-502/503/504/603/605/608/101 | ||
| Phosphite antioxidants | ||
| CHLUMIAO® 168 | CAS 31570-04-4 | Irganox 168 / Antioxidant 168 |
| CHLUMIAO® 626 | CAS 26741-53-7 | Ultranox 626 / Irgafos 126 |
| CHLUMIAO® 1790 | CAS 40601-76-1 | Antioxidant 1790/ Cyanox 1790 / Irganox 1790 |
| CHLUMIAO® 245 | CAS 36443-68-2 | Irganox 245 / Antioxidant 245 |
| High Performance Phosphites | ||
| CHLUMIAO® 1500 | CAS 96152-48-6 | Antioxidant 1500 |
| CHLUMIAO® 4500 | CAS 13003-12-8 | Antioxidant 4500 |
| CHLUMIAO® PDP | CAS 80584-86-7 | PowerNox DHOP / Antioxidant DHOP |
| CHLUMIAO® 618 | CAS 3806-34-6 | Antioxidant 618 |
| CHLUMIAO® DLP | CAS 21302-09-0 | Antioxidant DLP |
| CHLUMIAO® DPP | CAS 4712-55-4 | Antioxidant DPP |
| CHLUMIAO® DTDP | CAS 36432-46-9 | Antioxidant DTDP |
| CHLUMIAO® THOP | CAS 80584-85-6 | Antioxidant THOP |
| CHLUMIAO® TNPP | CAS 26523-78-4 | Antioxidant TNPP / Tris(nonylphenyl) phosphite |
| CHLUMIAO® PEP-36 | CAS 80693-00-1 | Antioxidant 636 / Antioxidant 636 |
| CHLUMIAO® 9228 | CAS 154862-43-8 | Irganox 9228 / Antioxidant 9228 |
| CHLUMIAO® PEPQ | CAS 119345-01-6 | Hostanox PEPQ / Antioxidant PEPQ |
| Low Impurity Phosphites | ||
| CHLUMIAO® DPOP | CAS 15647-08-2 | 2-ethylhexyl diphenyl phosphite |
| CHLUMIAO® 8621 | CAS 68123-00-2 | Antioxidant 8621 |
| CHLUMIAO® DPDP | CAS 26544-23-0 | Antioxidant DPDP |
| CHLUMIAO® PDDP | CAS 25550-98-5 | Antioxidant PDDP |
| CHLUMIAO® PDOP | CAS 3164-60-1 | Antioxidant PDOP |
| CHLUMIAO® TPP | CAS 101-02-0 | Antioxidant TPP |
| CHLUMIAO® Poly(dicyclopentadiene-co-p-cresol) | CAS 68610-51-5 | Poly(dicyclopentadiene-co-p-cresol) |
| CHLUMIAO® SEED | CAS 42774-15-2 | Antioxidant SEED / Omnistab LS 5519 / Light Stabilizer 856 |
| Inhibited phenolic Antioxidants | ||
| CHLUMIAO® 264 | CAS 128-37-0 | Antioxidant 264 / Butylated hydroxytoluene |
| CHLUMIAO® 2,6-Di-tert-butylphenol | CAS 128-39-2 | 2,6-Di-tert-butylphenol |
| CHLUMIAO® 300 | CAS 96-69-5 | Irganox 300 / Antioxidant 300 |
| CHLUMIAO® 2246 | CAS 119-47-1 | Irganox 2246 / BNX 2246 |
| CHLUMIAO® 1222 | CAS 976-56-7 | Antioxidant 1222 / Irganox 1222 |
| CHLUMIAO® 702 | CAS 118-82-1 | Irganox 702 / Antioxidant 702 / Ethanox 702 |
| CHLUMIAO® DBHQ | CAS 88-58-4 | Antioxidant DTBHQ |
| CHLUMIAO® MTBHQ | CAS 1948-33-0 | 2-tert-butylhydroquinone Industrial Grade |
| CHLUMIAO® 1076 | CAS 2082-79-3 | Irganox 1076 / Antioxidant 1076 |
| CHLUMIAO® 1010 | CAS 6683-19-8 | Irganox 1010 / Antioxidant 1010 |
| CHLUMIAO® 1330 | CAS 1709-70-2 | Irganox 1330 / Ethanox 330 |
| CHLUMIAO® 1520 | CAS 110553-27-0 | Irganox 1520 / Antioxidant 1520 |
| Phenol Free Phosphites Antioxidants | ||
| CHLUMIAO® 8608 | CAS 26544-27-4 | Antioxidant AO DPD / Everaox 202 |
| CHLUMIAO® 430 | CAS 36788-39-3 | Antioxidant 430 / WESTON 430 |
| CHLUMIAO® 8608T | CAS 1334238-11-7, 69439-68-5 | Antioxidant 8608T |
| CHLUMIAO® 8627 | CAS 68610-62-8 | Antioxidant 8627 |
| CHLUMIAO® TDP | CAS 25448-25-3 | Antioxidant TDP |
| CHLUMIAO® TLP | CAS 3076-63-9 | Antioxidant TLP |
| CHLUMIAO® TOP | CAS 301-13-3 | Antioxidant TOP |
| CHLUMIAO® TTDP | CAS 77745-66-5 | Antioxidant TTDP |
| Thiol esters Antioxidants | ||
| CHLUMIAO® DLTDP | CAS 123-28-4 | Dilauryl thiodipropionate |
| CHLUMIAO® DSTDP | CAS 693-36-7 | istearyl thiodipropionate/ Antioxidant DSTDP |
| Aminic Antioxidants | ||
| CHLUMIAO® 3114 | CAS 27676-62-6 | Irganox 3114 / Antioxidant 3114 |
| CHLUMIAO® 4,4′-biphenol | CAS 92-88-6 | 4,4′-biphenol |
| Metal deactivators Antioxidants | ||
| CHLUMIAO® 1098 | CAS 23128-74-7 | Irganox 1098 / Antioxidant 1098 |