{"id":5820,"date":"2022-12-30T10:40:43","date_gmt":"2022-12-30T10:40:43","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=5820"},"modified":"2026-04-28T06:29:02","modified_gmt":"2026-04-28T06:29:02","slug":"classification-and-mechanism-of-polymerization-inhibitors","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/tr\/classification-and-mechanism-of-polymerization-inhibitors\/","title":{"rendered":"Polimerizasyon inhibit\u00f6rlerinin s\u0131n\u0131fland\u0131r\u0131lmas\u0131 ve mekanizmas\u0131 nedir?"},"content":{"rendered":"

Polimerizasyon inhibit\u00f6rlerinin s\u0131n\u0131fland\u0131r\u0131lmas\u0131 ve mekanizmas\u0131 nedir?<\/strong><\/h1>\n

Depolama veya i\u015fleme ve safla\u015ft\u0131rma s\u00fcrecinde monomerlerin serbest radikal polimerizasyonu, genellikle \u0131\u015f\u0131k, \u0131s\u0131 ve di\u011fer fakt\u00f6rlerin rol\u00fc ve polimerizasyon nedeniyle, az miktarda polimerizasyon inhibit\u00f6r\u00fc eklemek bu y\u0131k\u0131c\u0131 reaksiyonu \u00f6nleyebilir. Polimerizasyon s\u00fcrecinde, baz\u0131 monomer polimerizasyonu, durdurma ihtiyac\u0131ndan sonra belirli bir d\u00f6n\u00fc\u015f\u00fcm oran\u0131na veya polimerizasyon inhibit\u00f6rlerinin zaman\u0131nda eklenmesi s\u00fcrece polimerizasyonu patlama e\u011filimine sahiptir, yak\u0131nda reaksiyonu sona erdirebilir veya durdurabilir. Polimerizasyon inhibit\u00f6rleri, birincil radikaller veya zincir radikalleri kararl\u0131 molek\u00fcllere d\u00f6n\u00fc\u015ft\u00fcr\u00fcr veya \u00e7ok d\u00fc\u015f\u00fck aktivite olu\u015fumu, kararl\u0131 bir radikal madde s\u0131n\u0131f\u0131n\u0131n polimerizasyon reaksiyonunu s\u00fcrd\u00fcrmek i\u00e7in yeterli de\u011fildir. Buna ek olarak, iyonik polimerizasyon i\u015fleminde bazen reaksiyonu sonland\u0131rmak veya reaksiyon \u00f6n polimer stabilitesini sa\u011flamak i\u00e7in, bazen basit, genellikle tart\u0131\u015f\u0131lmayan tip ve performans nedeniyle, genellikle stabilizat\u00f6rler olarak adland\u0131r\u0131lan bir engelleme maddesi olarak baz\u0131 asidik veya alkali bile\u015fikler eklenir.<\/p>\n

Depolamadaki polimerizasyon i\u015fleminde monomer, nakliye genellikle polimerizasyon ind\u00fcksiyon periyoduna eklenir (yani, bir s\u00fcre i\u00e7in s\u0131f\u0131r polimerizasyon oran\u0131), ind\u00fcksiyon periyodunun uzunlu\u011fu polimerizasyon inhibit\u00f6r\u00fcn\u00fcn i\u00e7eri\u011fi ile orant\u0131l\u0131d\u0131r, polimerizasyon inhibit\u00f6r\u00fcn\u00fcn t\u00fcketiminden sonra, ind\u00fcksiyon periyodunun sonu, yani polimerizasyon inhibit\u00f6r\u00fcn\u00fcn bulunmad\u0131\u011f\u0131 normal orana g\u00f6re. Bu nedenle, monomer kullan\u0131lmadan \u00f6nce polimerizasyon inhibit\u00f6r\u00fc uzakla\u015ft\u0131r\u0131lmal\u0131d\u0131r. Genel olarak, polimerizasyon inhibit\u00f6r\u00fc u\u00e7uculu\u011fu az olan kat\u0131 bir maddedir, bu nedenle monomerin dam\u0131t\u0131lmas\u0131 s\u0131ras\u0131nda uzakla\u015ft\u0131r\u0131labilir. Hidrokinonun polimerizasyonuna kar\u015f\u0131 yayg\u0131n olarak kullan\u0131lan diren\u00e7, suda \u00e7\u00f6z\u00fcn\u00fcr bir sodyum tuzu olu\u015fturmak i\u00e7in sodyum hidroksit ile reaksiyona girebilir, bu nedenle 5% ila 10% sodyum hidroksit \u00e7\u00f6zeltisi ile y\u0131kanarak \u00e7\u0131kar\u0131labilir. Bak\u0131r klor\u00fcr ve demir klor\u00fcr ve di\u011fer inorganik polimerizasyon inhibit\u00f6rleri de asit y\u0131kama ile giderilebilir.<\/p>\n

Yayg\u0131n olarak kullan\u0131lan polimerizasyon inhibit\u00f6rlerinin s\u0131n\u0131fland\u0131r\u0131lmas\u0131 ve mekanizmas\u0131 a\u015fa\u011f\u0131daki gibidir.<\/p>\n

(1) polifenoller polimerizasyon inhibit\u00f6r\u00fc polifenoller ve ikame edilmi\u015f fenoller yayg\u0131n olarak kullan\u0131lan bir s\u0131n\u0131ft\u0131r, iyi bir polimerizasyon inhibit\u00f6r\u00fcn\u00fcn etkisidir, ancak engelleme etkisini g\u00f6stermek i\u00e7in oksijen oldu\u011funda monomer i\u00e7inde \u00e7\u00f6z\u00fclmelidir. Polimerizasyon mekanizmas\u0131, fenol\u00fcn kar\u015f\u0131l\u0131k gelen kinona oksitlenmesi ve polimerizasyon rol\u00fcn\u00fc oynamak i\u00e7in birle\u015ftirilmi\u015f serbest radikal zinciridir. Fenolik inhibit\u00f6rlerin varl\u0131\u011f\u0131nda, polimerizasyon s\u00fcresini uzatmak i\u00e7in monomerde yeterli oksijen olmas\u0131n\u0131 sa\u011flamak i\u00e7in peroksit radikalleri h\u0131zla sonland\u0131r\u0131l\u0131r. \u00c7ok say\u0131da deneysel sonu\u00e7, fenollerin inhibit\u00f6r etkisinin asl\u0131nda bir antioksidan etki oldu\u011funu ve inhibit\u00f6r aktivitelerinin molek\u00fcler yap\u0131lar\u0131 ve \u00f6zellikleriyle ilgili oldu\u011funu kan\u0131tlam\u0131\u015ft\u0131r, bu nedenle hidrokinon gibi kinon benzeri yap\u0131lara kolayca oksitlenen fenoller, peroksil radikalleri ile y\u00fcksek reaktiviteye ve y\u00fcksek inhibit\u00f6r aktiviteye sahiptir. Benzen halkas\u0131 elektron emici gruba sahip oldu\u011funda, peroksi radikali ile reaksiyon aktivitesi d\u00fc\u015f\u00fckt\u00fcr ve engelleme aktivitesi de d\u00fc\u015f\u00fckt\u00fcr; aksine, itici elektron grubu ile peroksi radikali ile reaksiyon aktivitesi y\u00fcksektir ve engelleme aktivitesi de g\u00fc\u00e7l\u00fcd\u00fcr. Yayg\u0131n olarak kullan\u0131lan t\u00fcrler hidrokinon, p-tert-butilkatekol, 2,6-di-tert-butil-p-metilfenol, 4,4\u2032-di-tert-butilbifenil ve bisfenol A vb.dir.<\/p>\n

(2) kinon polimerizasyon inhibit\u00f6rleri kinon polimerizasyon inhibit\u00f6rleri yayg\u0131n olarak kullan\u0131lan molek\u00fcler polimerizasyon inhibit\u00f6rleridir, 0.01% ila 0.1% miktar\u0131 beklenen polimerizasyon engelleme etkisini elde edebilecektir, ancak farkl\u0131 monomer engelleme etkisi farkl\u0131d\u0131r. Benzokinon i\u00e7in stiren, vinil asetat polimerizasyonun etkili inhibit\u00f6r\u00fcd\u00fcr, ancak metil akrilat ve metil metakrilat sadece yava\u015f polimerizasyonda rol oynar. Kinon engelleme mekanizmas\u0131 tam olarak anla\u015f\u0131lamam\u0131\u015ft\u0131r, kinon ve radikallerin kinon tipi veya yar\u0131 kinon tipi radikaller \u00fcretmek i\u00e7in ekleme veya orant\u0131s\u0131zl\u0131k reaksiyonlar\u0131na girmesi ve daha sonra polimerizasyonu engellemede rol oynayan inaktif \u00fcr\u00fcnler elde etmek i\u00e7in reaktif radikallerle birle\u015fmesi olabilir. Kinonun agregasyonu bloke etme yetene\u011fi hem kinonun yap\u0131s\u0131 hem de monomerin do\u011fas\u0131 ile ilgilidir. Kinon \u00e7ekirde\u011fi elektrofilik \u00f6zelliklere sahiptir ve kinon halkas\u0131 \u00fczerindeki s\u00fcbstit\u00fcentler elektrofiliklik \u00fczerinde bir etkiye sahiptir, bu da b\u00f6lge engelleme etkisi ile birlikte keton engelleme etkinli\u011finin farkl\u0131l\u0131\u011f\u0131na neden olur. P-benzokinon molek\u00fcl\u00fc ba\u015f\u0131na sonland\u0131r\u0131labilen radikal say\u0131s\u0131 1'den fazlad\u0131r, hatta 2'ye kadar \u00e7\u0131kabilir. Tetraklorobenzokinon ve 1,4-naftokinon, polimerizasyonun engellenmesinde iyi bir rol oynamak ve depolama stabilitesini art\u0131rmak i\u00e7in stiren i\u00e7eren doymam\u0131\u015f polyester re\u00e7inelere eklenebilir. Tetraklorobenzokinon vinil asetat i\u00e7in etkili bir polimerizasyon inhibit\u00f6r\u00fcd\u00fcr, ancak akrilonitril \u00fczerinde polimerizasyonu engelleyici etkisi yoktur.<\/p>\n

(3) aromatik amin polimerizasyon inhibit\u00f6rleri aromatik amin polimerizasyon inhibit\u00f6rleri hem alken monomer inhibit\u00f6rleri, hem de polimer malzemeler, antioksidan ya\u015fland\u0131rma ajan\u0131d\u0131r. Aromatik amin bile\u015fikleri, polimerizasyonu engellemede fenoller kadar etkili de\u011fildir, sadece vinil asetat, izopren, b\u00fctadien, stiren i\u00e7in etkilidir, ancak akrilatlar ve metakrilatlar \u00fczerinde engelleme etkisi yoktur. Nitrobenzen, serbest radikallerle kararl\u0131 nitroksit radikalleri olu\u015fturarak bir polimerizasyon inhibit\u00f6r\u00fc olarak i\u015flev g\u00f6r\u00fcr. Aromatik aminler ve fenoller polimerizasyon mekanizmalar\u0131nda benzerdir ve baz\u0131 monomerler i\u00e7in, ikisinin belirli bir oranda kullan\u0131lmas\u0131 polimerizasyon \u00fczerinde tek bir kullan\u0131mdan daha iyi bir etkiye sahip olacakt\u0131r. \u00d6rne\u011fin, hidrokinon ve difenilamin kar\u0131\u015f\u0131m\u0131 veya tert-butil katekol ve fenotiyazin kar\u0131\u015f\u0131m\u0131, polimerizasyonun etkisi 300 kat artt\u0131\u011f\u0131nda tek ba\u015f\u0131na oldu\u011fundan daha iyidir. Aromatik amin polimerizasyon inhibit\u00f6rlerinin engelleme aktivitesi, molek\u00fcler s\u00fcbstit\u00fcentlerinin do\u011fas\u0131 ile ilgilidir ve anilinin engelleme aktivitesi, para pozisyonunda elektron itici bir gruba sahip oldu\u011funda artacakt\u0131r. Amino grubundaki hidrojen metil ile de\u011fi\u015ftirildi\u011finde, engelleme aktivitesi \u00f6nemli \u00f6l\u00e7\u00fcde azal\u0131r. Anilin i\u00e7in, amino grubunun aktivitesi 1-pozisyonunda 2-pozisyonundan daha y\u00fcksektir ve aktivite daha fazla amino grubu ile artar ve naftalin halkas\u0131 elektron emici bir grup ta\u015f\u0131d\u0131\u011f\u0131nda \u00f6nemli \u00f6l\u00e7\u00fcde azal\u0131r. P-fenilendiaminin amino grubu \u00fczerindeki hidrojen, alkil, aril t\u00fcrevleri ile ikame edildi\u011finde, engelleme aktivitesi daha y\u00fcksektir. Yayg\u0131n olarak kullan\u0131lan aril amin polimerizasyon inhibit\u00f6rleri aras\u0131nda p-toluidin, difenilamin, benzidin, p-fenilendiamin, N-nitrosodifenilamin vb. bulunur.<\/p>\n

(4) Serbest radikal polimerizasyon inhibit\u00f6r\u00fc 1,1-difenil-2-trinitrofenilhidrazin tipik bir serbest radikal tipi polimerizasyon inhibit\u00f6r\u00fcd\u00fcr. G\u00fc\u00e7l\u00fc konjugat stabilizasyonu ve b\u00fcy\u00fck uzaysal alan direnci nedeniyle, bu bile\u015fik kendi ba\u015f\u0131na dimerize olamayan ve monomerleri ba\u015flatamayan, ancak ideal bir polimerizasyon inhibit\u00f6r\u00fc olan aktif radikalleri yakalayabilen serbest radikaller \u015feklinde bulunabilir. Serbest radikal tipi polimerizasyon inhibit\u00f6r\u00fc engelleme etkisi m\u00fckemmel olmas\u0131na ra\u011fmen, haz\u0131rlanmas\u0131 zor, pahal\u0131, monomer rafine etme, depolama ve ta\u015f\u0131ma, polimerizasyonun sonland\u0131r\u0131lmas\u0131, ba\u015flatma oran\u0131n\u0131n belirlenmesi ile s\u0131n\u0131rl\u0131 olan bu inhibit\u00f6r daha az kullan\u0131l\u0131r.<\/p>\n

(5) inorganik bile\u015fikler polimerizasyon inhibit\u00f6r\u00fc inorganik tuzlar, y\u00fck transferi ve polimerizasyonun rol\u00fc, ferrik klor\u00fcr polimerizasyon engelleme etkinli\u011fi ve kimyasal doz 1,1 serbest radikalleri ile ortadan kald\u0131r\u0131labilir. Sodyum s\u00fclfat, sodyum s\u00fclfit, amonyum tiyosiyanat sulu faz polimerizasyon inhibit\u00f6r\u00fc olarak kullan\u0131labilir. Sodyum s\u00fclf\u00fcr, sodyum ditiyokarbamat ve metilen mavisi ve baz\u0131 monomerlerdeki di\u011fer azotlu, k\u00fck\u00fcrtl\u00fc bile\u015fikler de etkili polimerizasyon engelleme etkisine sahiptir. De\u011fi\u015fken de\u011ferlikli ge\u00e7i\u015f metal tuzlar\u0131 baz\u0131 monomerler \u00fczerinde polimerizasyonu engelleyici etkiye sahiptir \u00e7\u00fcnk\u00fc bu maddeler elektron transferi ile aktif zinciri patlatarak polimerizasyon reaksiyonunu sonland\u0131rabilir. Bak\u0131r oksit, kobalt metakrilat vb. gibi di\u011fer bile\u015fikler iyi polimerizasyon engelleme etkisine sahiptir.<\/p>\n

Polimerizasyon inhibit\u00f6r\u00fc se\u00e7iminin esas olarak y\u00fcksek bir polimerizasyon engelleme verimlili\u011fine sahip olmas\u0131 gerekir, ayr\u0131ca monomerdeki \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fcn\u00fc ve monomerin uyarlanabilirli\u011fini de dikkate almal\u0131d\u0131r, dam\u0131tma veya kimyasal polimerizasyon inhibit\u00f6r\u00fc y\u00f6ntemi ile monomerden kolayca \u00e7\u0131kar\u0131labilir. Oda s\u0131cakl\u0131\u011f\u0131nda bir engelleyici olarak hareket edebilen ve reaksiyon s\u0131cakl\u0131\u011f\u0131nda h\u0131zla ayr\u0131\u015fabilen bir polimerizasyon inhibit\u00f6r\u00fc se\u00e7mek en iyisidir, b\u00f6ylece sorunu azaltmak ve sorunsuz polimerizasyon reaksiyonunu sa\u011flamak i\u00e7in monomerden \u00e7\u0131kar\u0131labilir.<\/p>\n

\u2460Monomer ve re\u00e7ine ile kar\u0131\u015fabilirlik iyidir, sadece kar\u0131\u015fabilir polimerizasyonda rol oynayabilir.<\/p>\n

\u2461Polimerizasyon reaksiyonunun olu\u015fmas\u0131n\u0131 etkili bir \u015fekilde \u00f6nleyebilir, b\u00f6ylece monomer, re\u00e7ine, em\u00fclsiyon veya yap\u0131\u015ft\u0131r\u0131c\u0131 yeterli depolama s\u00fcresine sahip olur.<\/p>\n

\u2462 Monomerdeki polimerizasyon inhibit\u00f6r\u00fcn\u00fcn \u00e7\u0131kar\u0131lmas\u0131 kolayd\u0131r veya polimerizasyon aktivitesini etkilemez. Etkili polimerizasyon inhibit\u00f6r\u00fcn\u00fc oda s\u0131cakl\u0131\u011f\u0131nda ve polimerizasyon inhibit\u00f6r\u00fcn\u00fc kaybetmek i\u00e7in uygun y\u00fcksek bir s\u0131cakl\u0131kta se\u00e7mek en iyisidir, b\u00f6ylece inhibit\u00f6r\u00fcn kullan\u0131mdan \u00f6nce \u00e7\u0131kar\u0131lmas\u0131 gerekmez. \u00d6rne\u011fin, tert-b\u00fctil katekol, p-fenol monob\u00fctil eter bu tip bir polimerizasyon inhibit\u00f6r\u00fcd\u00fcr.<\/p>\n

\u2463 Yap\u0131\u015ft\u0131r\u0131c\u0131lar\u0131n ve s\u0131zd\u0131rmazl\u0131k maddelerinin k\u00fcrlenmesinin fiziksel ve mekanik \u00f6zelliklerini etkilemez. Yap\u0131\u015ft\u0131r\u0131c\u0131lar\u0131n haz\u0131rlanmas\u0131nda polimer inhibit\u00f6r\u00fc y\u00fcksek s\u0131cakl\u0131k nedeniyle oksidasyon s\u00fcrecinde renk de\u011fi\u015fikli\u011fi ve \u00fcr\u00fcn\u00fcn g\u00f6r\u00fcn\u00fcm\u00fcn\u00fc etkiler.<\/p>\n

\u2464 Birlikte kullan\u0131lan birka\u00e7 inhibit\u00f6r, polimerizasyonun etkisini \u00f6nemli \u00f6l\u00e7\u00fcde art\u0131rabilir. \u00d6rne\u011fin, hidrokinon, tert-butil katekol ve bak\u0131r naftenat 3 \u00e7e\u015fit inhibit\u00f6r i\u00e7eren doymam\u0131\u015f polyester re\u00e7ine, hidrokinon aktivitesi en g\u00fc\u00e7l\u00fc olan\u0131d\u0131r, stiren ve polyester ile kar\u0131\u015fabilir, kopolimerizasyon olmadan 1 dakika i\u00e7inde yakla\u015f\u0131k 130 \u2103 y\u00fcksek s\u0131cakl\u0131klara dayanabilir, g\u00fcvenli bir \u015fekilde kar\u0131\u015ft\u0131r\u0131labilir seyreltme. Tert-butil katekol y\u00fcksek s\u0131cakl\u0131klarda zay\u0131ft\u0131r, ancak biraz daha d\u00fc\u015f\u00fck bir s\u0131cakl\u0131kta (\u00f6rne\u011fin, 60 \u2103), engelleme etkisi hidrokinondan 25 kat daha y\u00fcksektir ve daha uzun bir depolama s\u00fcresine sahip olabilir. Bak\u0131r naftenat oda s\u0131cakl\u0131\u011f\u0131nda bir engelleyici ve y\u00fcksek s\u0131cakl\u0131kta bir destekleyici olarak hareket eder: ayr\u0131ca, \u00f6rne\u011fin oksijen varl\u0131\u011f\u0131nda. Tert-butil katekol ve fenotiyazin, hidrokinon ve difenilamin kar\u0131\u015f\u0131k kullan\u0131m\u0131nda, engelleme etkisi tek ba\u015f\u0131na kullan\u0131mdan yakla\u015f\u0131k 300 kat daha y\u00fcksektir.<\/p>\n

\u00d6rne\u011fin, 10-4 mol\/L'deki iyot etkili bir polimerizasyon inhibit\u00f6r\u00fcd\u00fcr, ancak bu miktardan fazlas\u0131 polimerizasyon reaksiyonlar\u0131n\u0131 tetikleyebilir. \u0130yot genellikle tek ba\u015f\u0131na kullan\u0131lmaz, ancak \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc art\u0131rmak ve polimerizasyon engelleme etkinli\u011fini geli\u015ftirmek i\u00e7in az miktarda potasyum iyod\u00fcr eklenmelidir.<\/p>\n

(7) Toksik de\u011fildir, zarars\u0131zd\u0131r, \u00e7evre kirlili\u011fi yaratmaz.<\/p>\n

\u2467 \u0130stikrarl\u0131 performans, ucuz ve elde edilmesi kolay.<\/p>\n

 <\/p>\n

UV Monomer<\/span><\/a> Ayn\u0131 seri \u00fcr\u00fcnler<\/strong><\/h2>\n

 <\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
Politiyol\/Polimerkaptan<\/strong><\/td>\n<\/td>\n<\/td>\n<\/tr>\n
DMES Monomer<\/a><\/span><\/td>\nBis(2-mercaptoethyl) sulfide<\/td>\n3570-55-6<\/td>\n<\/tr>\n
DMPT Monomer<\/a><\/span><\/td>\nTHIOCURE DMPT<\/td>\n131538-00-6<\/td>\n<\/tr>\n
PETMP Monomer<\/a><\/span><\/td>\n<\/td>\n7575-23-7<\/td>\n<\/tr>\n
PM839 Monomer<\/a><\/span><\/td>\nPolioksi (metil-1,2-etanediyl)<\/td>\n72244-98-5<\/td>\n<\/tr>\n
Monofonksiyonel Monomer<\/strong><\/td>\n<\/td>\n<\/td>\n<\/tr>\n
HEMA Monomer<\/a><\/span><\/td>\n2-hidroksietil metakrilat<\/td>\n868-77-9<\/td>\n<\/tr>\n
HPMA Monomer<\/a><\/span><\/td>\n2-Hidroksipropil metakrilat<\/td>\n27813-02-1<\/td>\n<\/tr>\n
THFA Monomer<\/a><\/span><\/td>\nTetrahidrofurfuril akrilat<\/td>\n2399-48-6<\/td>\n<\/tr>\n
HDCPA Monomer<\/a><\/span><\/td>\nHidrojenlenmi\u015f disiklopentenil akrilat<\/td>\n79637-74-4<\/td>\n<\/tr>\n
DCPMA Monomer<\/a><\/span><\/td>\nDihydrodicyclopentadienyl methacrylate<\/td>\n30798-39-1<\/td>\n<\/tr>\n
DCPA Monomer<\/a><\/span><\/td>\nDihidrodisiklopentadienil Akrilat<\/td>\n12542-30-2<\/td>\n<\/tr>\n
DCPEMA Monomer<\/a><\/span><\/td>\nDisiklopenteniloksietil Metakrilat<\/td>\n68586-19-6<\/td>\n<\/tr>\n
DCPEOA Monomer<\/a><\/span><\/td>\nDisiklopenteniloksietil Akrilat<\/td>\n65983-31-5<\/td>\n<\/tr>\n
NP-4EA Monomer<\/a><\/span><\/td>\n(4) etoksillenmi\u015f nonilfenol<\/td>\n50974-47-5<\/td>\n<\/tr>\n
LA Monomer<\/td>\nLauril akrilat \/ Dodesil akrilat<\/td>\n2156-97-0<\/td>\n<\/tr>\n
THFMA Monomer<\/a><\/span><\/td>\nTetrahidrofurfuril metakrilat<\/td>\n2455-24-5<\/td>\n<\/tr>\n
PHEA Monomer<\/span><\/a><\/td>\n2-FENOKSIETIL AKRILAT<\/td>\n48145-04-6<\/td>\n<\/tr>\n
LMA Monomer<\/a><\/span><\/td>\nLauril metakrilat<\/td>\n142-90-5<\/td>\n<\/tr>\n
IDA Monomer<\/a><\/span><\/td>\n\u0130zodesil akrilat<\/td>\n1330-61-6<\/td>\n<\/tr>\n
IBOMA Monomer<\/a><\/span><\/td>\n\u0130zobornil metakrilat<\/td>\n7534-94-3<\/td>\n<\/tr>\n
IBOA Monomer<\/a><\/span><\/td>\n\u0130zobornil akrilat<\/td>\n5888-33-5<\/td>\n<\/tr>\n
EOEOEA Monomer<\/a><\/span><\/td>\n2-(2-Etoksietoksi)etil akrilat<\/td>\n7328-17-8<\/td>\n<\/tr>\n
\u00c7ok fonksiyonlu monomer<\/strong><\/td>\n<\/td>\n<\/td>\n<\/tr>\n
DPHA Monomer<\/a><\/span><\/td>\n<\/td>\n29570-58-9<\/td>\n<\/tr>\n
DI-TMPTA Monomer<\/a><\/span><\/td>\nDI(TRIMETILOLPROPAN) TETRAAKRILAT<\/td>\n94108-97-1<\/td>\n<\/tr>\n
Akrilamid monomer<\/strong><\/td>\n<\/td>\n<\/td>\n<\/tr>\n
ACMO Monomer<\/a><\/span><\/td>\n4-akriloilmorfolin<\/td>\n5117-12-4<\/td>\n<\/tr>\n
Di-fonksiyonel Monomer<\/strong><\/td>\n<\/td>\n<\/td>\n<\/tr>\n
PEGDMA Monomer<\/a><\/span><\/td>\nPoli(etilen glikol) dimetakrilat<\/td>\n25852-47-5<\/td>\n<\/tr>\n
TPGDA Monomer<\/a><\/span><\/td>\nTripropilen glikol diakrilat<\/td>\n42978-66-5<\/td>\n<\/tr>\n
TEGDMA Monomer<\/a><\/span><\/td>\nTrietilen glikol dimetakrilat<\/td>\n109-16-0<\/td>\n<\/tr>\n
PO2-NPGDA Monomer<\/span><\/a><\/td>\nPropoksilat neopentilen glikol diakrilat<\/td>\n84170-74-1<\/td>\n<\/tr>\n
PEGDA Monomer<\/a><\/span><\/td>\nPolietilen Glikol Diakrilat<\/td>\n26570-48-9<\/td>\n<\/tr>\n
PDDA Monomer<\/a><\/span><\/td>\nFtalat dietilen glikol diakrilat<\/td>\n<\/td>\n<\/tr>\n
NPGDA Monomer<\/a><\/span><\/td>\nNeopentil glikol diakrilat<\/td>\n2223-82-7<\/td>\n<\/tr>\n
HDDA Monomer<\/a><\/span><\/td>\nHeksametilen Diakrilat<\/td>\n13048-33-4<\/td>\n<\/tr>\n
EO4-BPADA Monomer<\/span><\/a><\/td>\nETOKSILLENMI\u015e (4) BISFENOL A DIAKRILAT<\/td>\n64401-02-1<\/td>\n<\/tr>\n
EO10-BPADA Monomer<\/a><\/span><\/td>\nETOKSILLENMI\u015e (10) BISFENOL A DIAKRILAT<\/td>\n64401-02-1<\/td>\n<\/tr>\n
EGDMA Monomer<\/a><\/span><\/td>\nEtilen glikol dimetakrilat<\/td>\n97-90-5<\/td>\n<\/tr>\n
DPGDA Monomer<\/a><\/span><\/td>\nDipropilen Glikol Dienoat<\/td>\n57472-68-1<\/td>\n<\/tr>\n
Bis-GMA Monomer<\/a><\/span><\/td>\nBisfenol A Glisidil Metakrilat<\/td>\n1565-94-2<\/td>\n<\/tr>\n
\u00dc\u00e7 Fonksiyonlu Monomer<\/strong><\/td>\n<\/td>\n<\/td>\n<\/tr>\n
TMPTMA Monomer<\/a><\/span><\/td>\nTrimetilolpropan trimetakrilat<\/td>\n3290-92-4<\/td>\n<\/tr>\n
TMPTA Monomer<\/a><\/span><\/td>\nTrimetilolpropan triakrilat<\/td>\n15625-89-5<\/td>\n<\/tr>\n
PETA Monomer<\/a><\/span><\/td>\n<\/td>\n3524-68-3<\/td>\n<\/tr>\n
GPTA (G3POTA) Monomer<\/a><\/span><\/td>\nGLISERIL PROPOKSI TRIAKRILAT<\/td>\n52408-84-1<\/td>\n<\/tr>\n
EO3-TMPTA Monomer<\/a><\/span><\/td>\nEtoksillenmi\u015f trimetilolpropan triakrilat<\/td>\n28961-43-5<\/td>\n<\/tr>\n
Fotorezist Monomer<\/strong><\/td>\n<\/td>\n<\/td>\n<\/tr>\n
IPAMA Monomer<\/a><\/span><\/td>\n2-izopropil-2-adamantil metakrilat<\/td>\n297156-50-4<\/td>\n<\/tr>\n
ECPMA Monomer<\/a><\/span><\/td>\n1-Etilsiklopentil Metakrilat<\/td>\n266308-58-1<\/td>\n<\/tr>\n
ADAMA Monomer<\/a><\/span><\/td>\n1-Adamantil Metakrilat<\/td>\n16887-36-8<\/td>\n<\/tr>\n
Metakrilat monomer<\/strong><\/td>\n<\/td>\n<\/td>\n<\/tr>\n
TBAEMA Monomer<\/a><\/span><\/td>\n2-(Tert-b\u00fctilamino)etil metakrilat<\/td>\n3775-90-4<\/td>\n<\/tr>\n
NBMA Monomer<\/a><\/span><\/td>\nn-B\u00fctil metakrilat<\/td>\n97-88-1<\/td>\n<\/tr>\n
MEMA Monomer<\/a><\/span><\/td>\n2-Metoksietil Metakrilat<\/td>\n6976-93-8<\/td>\n<\/tr>\n
i-BMA Monomer<\/a><\/span><\/td>\n\u0130zob\u00fctil metakrilat<\/td>\n97-86-9<\/td>\n<\/tr>\n
EHMA Monomer<\/a><\/span><\/td>\n2-Etilheksil metakrilat<\/td>\n688-84-6<\/td>\n<\/tr>\n
EGDMP Monomer<\/a><\/span><\/td>\nEtilen glikol Bis(3-merkaptopropiyonat)<\/td>\n22504-50-3<\/td>\n<\/tr>\n
EEMA Monomer<\/a><\/span><\/td>\n2-etoksietil 2-metilprop-2-enoat<\/td>\n2370-63-0<\/td>\n<\/tr>\n
DMAEMA Monomer<\/a><\/span><\/td>\nN,M-Dimetilaminoetil metakrilat<\/td>\n2867-47-2<\/td>\n<\/tr>\n
DEAM Monomer<\/a><\/span><\/td>\nDietilaminoetil metakrilat<\/td>\n105-16-8<\/td>\n<\/tr>\n
CHMA Monomer<\/a><\/span><\/td>\nSikloheksil metakrilat<\/td>\n101-43-9<\/td>\n<\/tr>\n
BZMA Monomer<\/a><\/span><\/td>\nBenzil metakrilat<\/td>\n2495-37-6<\/td>\n<\/tr>\n
BDDMP Monomer<\/a><\/span><\/td>\n1,4-B\u00fctandiol Di(3-merkaptopropiyonat)<\/td>\n92140-97-1<\/td>\n<\/tr>\n
BDDMA Monomer<\/a><\/span><\/td>\n1,4-B\u00fctandioldimetakrilat<\/td>\n2082-81-7<\/td>\n<\/tr>\n
AMA Monomer<\/a><\/span><\/td>\nAlil metakrilat<\/td>\n96-05-9<\/td>\n<\/tr>\n
AAEM Monomer<\/a><\/span><\/td>\nAsetilasetoksietil metakrilat<\/td>\n21282-97-3<\/td>\n<\/tr>\n
Akrilatlar Monomer<\/strong><\/td>\n<\/td>\n<\/tr>\n
IBA Monomer<\/a><\/span><\/td>\n\u0130zob\u00fctil akrilat<\/td>\n106-63-8<\/td>\n<\/tr>\n
EMA Monomer<\/a><\/span><\/td>\nEtil metakrilat<\/td>\n97-63-2<\/td>\n<\/tr>\n
DMAEA Monomer<\/a><\/span><\/td>\nDimetilaminoetil akrilat<\/td>\n2439-35-2<\/td>\n<\/tr>\n
DEAEA Monomer<\/a><\/span><\/td>\n2-(dietilamino)etil prop-2-enoat<\/td>\n2426-54-2<\/td>\n<\/tr>\n
CHA Monomer<\/a><\/span><\/td>\nsikloheksil prop-2-enoat<\/td>\n3066-71-5<\/td>\n<\/tr>\n
BZA Monomer<\/a><\/span><\/td>\nbenzil prop-2-enoat<\/td>\n2495-35-4<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

 <\/p>\n

 <\/p>\n

\u015eimdi Bize Ula\u015f\u0131n!<\/b><\/strong><\/h2>\n

COA, MSDS veya TDS'ye ihtiyac\u0131n\u0131z varsa, l\u00fctfen a\u015fa\u011f\u0131daki forma ileti\u015fim bilgilerinizi girin, genellikle 24 saat i\u00e7inde sizinle ileti\u015fime ge\u00e7ece\u011fiz. Bana e-posta da g\u00f6nderebilirsiniz info@longchangchemical.com<\/a><\/span> \u00c7al\u0131\u015fma saatleri i\u00e7inde (8:30 - 6:00 UTC+8 Pzt.~Sat.) veya h\u0131zl\u0131 yan\u0131t almak i\u00e7in web sitesi canl\u0131 sohbetini kullan\u0131n.<\/b><\/strong><\/h4>","protected":false},"excerpt":{"rendered":"

Free radical polymerization of monomers in the storage or processing and purification process, often due to the role of light, heat and other factors and polymerization, adding a small amount<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[114],"tags":[],"class_list":["post-5820","post","type-post","status-publish","format-standard","hentry","category-catalysts-chemical-auxiliary-agents"],"yoast_head":"\nWhat is the classification and mechanism of polymerization inhibitors? - Longchang Chemical<\/title>\n<meta name=\"description\" content=\"Free radical polymerization of monomers in the storage or processing and purification process, often due to the role of light, heat and other factors an...\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/longchangchemical.com\/tr\/classification-and-mechanism-of-polymerization-inhibitors\/\" \/>\n<meta property=\"og:locale\" content=\"tr_TR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"What is the classification and mechanism of polymerization inhibitors? 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