{"id":5698,"date":"2022-10-30T05:41:37","date_gmt":"2022-10-30T05:41:37","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=5698"},"modified":"2026-04-28T10:42:10","modified_gmt":"2026-04-28T10:42:10","slug":"how-to-inhibit-oxygen-blocking","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/tr\/how-to-inhibit-oxygen-blocking\/","title":{"rendered":"Oksijen blokaj\u0131 nas\u0131l engellenir?"},"content":{"rendered":"<h1><strong>Oksijen blokaj\u0131 nas\u0131l engellenir?<\/strong><\/h1>\n<p><!-- lc-qa-start --><\/p>\n<p><strong>Quick answer:<\/strong> For practical formulation work, photoinitiator screening starts with the light source and film build, then checks yellowing, adhesion, and cure completeness under real production conditions.<\/p>\n<p><!-- lc-qa-end --><\/p>\n<p>Oksijen engelleme ayn\u0131 zamanda oksijen inhibisyonu olarak da adland\u0131r\u0131l\u0131r. Y\u00fczey katman\u0131ndaki y\u00fcksek oksijen konsantrasyonu nedeniyle, oksijen inhibisyonu alt katman\u0131n k\u00fcrlenmesine, y\u00fczeyin hala k\u00fcrlenmemi\u015f ve yap\u0131\u015fkan olmas\u0131na ve kuru olmamas\u0131na yol a\u00e7acakt\u0131r. Oksijen inhibisyonu sadece k\u00fcrlenme s\u00fcresini uzatmakla kalmaz, ayn\u0131 zamanda sertlik, a\u015f\u0131nma direnci, \u00e7izilme direnci vb. gibi k\u00fcrlenmi\u015f y\u00fczey katman\u0131n\u0131n performans\u0131n\u0131 da etkileyebilir. Neredeyse t\u00fcm geleneksel fotoba\u015flat\u0131c\u0131 malzemelerin k\u00fcrlenme reaksiyonu oksijenden etkilenir.<br \/>\nOksijen blokajl\u0131 agregasyon sorununu \u00e7\u00f6zmek i\u00e7in esas olarak reaksiyon mekanizmas\u0131, reaksiyon h\u0131z\u0131, k\u00fcrleme s\u00fcreci olmak \u00fczere \u00fc\u00e7 y\u00f6n\u00fc de\u011fi\u015ftirmek gerekir.<br \/>\n1. Reaksiyon mekanizmas\u0131n\u0131 de\u011fi\u015ftirin: form\u00fclasyon viskozitesi gibi y\u00fczey oksijen engelleme agregasyonu olgusunu bast\u0131rmak i\u00e7in fotoba\u015flat\u0131c\u0131 sistemini iyile\u015ftirin: d\u00fc\u015f\u00fck viskoziteli form\u00fclasyonlarda, oksijen dif\u00fczyon h\u0131z\u0131 daha h\u0131zl\u0131 olacakt\u0131r, bu nedenle daha y\u00fcksek viskoziteli form\u00fclasyonlarda oksijen engelleme durumu azalacakt\u0131r. S\u0131cakl\u0131ktaki bir art\u0131\u015f sistemin viskozitesini azaltt\u0131\u011f\u0131ndan, daha d\u00fc\u015f\u00fck s\u0131cakl\u0131klarda k\u00fcrleme daha az oksijen blokaj\u0131 ile sonu\u00e7lanacakt\u0131r.<br \/>\n2. Reaksiyon h\u0131z\u0131n\u0131 de\u011fi\u015ftirin: ba\u015flat\u0131c\u0131 konsantrasyonunu art\u0131r\u0131n veya \u0131\u015f\u0131k yo\u011funlu\u011funu art\u0131r\u0131n, \u00e7\u00fcnk\u00fc oksijen engellemesi oksijen ve serbest radikaller aras\u0131ndaki reaksiyondan kaynaklan\u0131r, daha sonra y\u00fcksek bir fotoba\u015flat\u0131c\u0131 konsantrasyonu daha fazla serbest radikal \u00fcretebilir, bu da oksijen t\u00fcketimini \u00f6nler ve oksijenin kaplamaya dif\u00fczyonunu \u00f6nler ve sonunda oksijen engellemesinin \u00fcstesinden gelme etkisini elde eder. Elbette, serbest radikal \u00fcretim oran\u0131 ve fotoba\u015flat\u0131c\u0131 t\u00fcr\u00fcn\u00fcn de b\u00fcy\u00fck bir ili\u015fkisi vard\u0131r; modifiye edilmi\u015f bir k\u00fcrleme re\u00e7inesi se\u00e7ebilir ve ard\u0131ndan oksijen t\u00fcketen monomerler veya gruplar ekleyebilirsiniz; \u0131\u015f\u0131kla k\u00fcrleme sistemine bir veya daha fazla oksijen tutucu eklemek oksijen engelleme etkisini hafifletebilir<br \/>\n3. boya hassasla\u015ft\u0131r\u0131c\u0131: Baz\u0131 pigment hassasla\u015ft\u0131r\u0131c\u0131lar\u0131n (1,3-difenilizobenzofuran gibi) varl\u0131\u011f\u0131nda, fotoba\u015flat\u0131c\u0131 i\u015flevine sahip \u00fcr\u00fcnler (1,2-dibenzoilbenzen gibi) \u00fcretilebilir, b\u00f6ylece oksijen engelleme rol\u00fc hafifletilebilir. Ancak, bu y\u00f6ntem form\u00fclasyona bir miktar renk getirece\u011finden kullan\u0131m\u0131 s\u0131n\u0131rl\u0131d\u0131r.<br \/>\n4. K\u00fcrleme s\u00fcrecini de\u011fi\u015ftirin: inert gaz koruma y\u00f6ntemi; y\u00fczen mum y\u00f6ntemi; laminasyon y\u00f6ntemi; g\u00fc\u00e7l\u00fc \u0131\u015f\u0131k \u0131\u015f\u0131nlama y\u00f6ntemi; ad\u0131m ad\u0131m \u0131\u015f\u0131nlama y\u00f6ntemi<br \/>\nAncak farkl\u0131 ba\u015fa \u00e7\u0131kma y\u00f6ntemlerinin art\u0131lar\u0131 ve eksileri vard\u0131r.<\/p>\n<table style=\"border-collapse: collapse; width: 543.77pt;\" border=\"0\" width=\"725\" cellspacing=\"0\" cellpadding=\"0\">\n<tbody>\n<tr style=\"height: 14.25pt;\">\n<td class=\"et2\" style=\"height: 14.25pt; width: 114.75pt;\" width=\"153\" height=\"19\">Y\u00f6ntem<\/td>\n<td class=\"et3\" style=\"width: 207.00pt;\" width=\"276\">Avantajlar<\/td>\n<td class=\"et3\" style=\"width: 222.00pt;\" width=\"296\">Dezavantajlar<\/td>\n<\/tr>\n<tr style=\"height: 26.25pt;\">\n<td class=\"et4\" style=\"height: 26.25pt; width: 114.75pt;\" width=\"153\" height=\"35\">\u0130nert gaz korumas\u0131<\/td>\n<td class=\"et5\" style=\"width: 207.00pt;\" width=\"276\">\u00dcr\u00fcn performans\u0131 \u00fczerinde olumsuz etki yok<\/td>\n<td class=\"et5\" style=\"width: 222.00pt;\" width=\"296\">Pahal\u0131; uygulamas\u0131 zor<\/td>\n<\/tr>\n<tr style=\"height: 26.25pt;\">\n<td class=\"et4\" style=\"height: 26.25pt; width: 114.75pt;\" width=\"153\" height=\"35\">Y\u00fczen balmumu y\u00f6ntemi<\/td>\n<td class=\"et5\" style=\"width: 207.00pt;\" width=\"276\">Ucuz<\/td>\n<td class=\"et5\" style=\"width: 222.00pt;\" width=\"296\">\u00dcr\u00fcn performans\u0131n\u0131 etkiler; ge\u00e7i\u015fin tamamlanmas\u0131 zaman al\u0131r<\/td>\n<\/tr>\n<tr style=\"height: 26.25pt;\">\n<td class=\"et4\" style=\"height: 26.25pt; width: 114.75pt;\" width=\"153\" height=\"35\">Kaplama y\u00f6ntemi<\/td>\n<td class=\"et5\" style=\"width: 207.00pt;\" width=\"276\">Membran \u00fcr\u00fcn\u00fcn bir par\u00e7as\u0131 oldu\u011funda iyi bir \u00e7\u00f6z\u00fcm<\/td>\n<td class=\"et5\" style=\"width: 222.00pt;\" width=\"296\">Malzeme maliyeti ve membran \u00e7\u0131karma<\/td>\n<\/tr>\n<tr style=\"height: 26.25pt;\">\n<td class=\"et4\" style=\"height: 26.25pt; width: 114.75pt;\" width=\"153\" height=\"35\">Ba\u015flat\u0131c\u0131 konsantrasyonunu art\u0131r\u0131n<\/td>\n<td class=\"et5\" style=\"width: 207.00pt;\" width=\"276\">Uygulamas\u0131 kolay<\/td>\n<td class=\"et5\" style=\"width: 222.00pt;\" width=\"296\">Artan kal\u0131nt\u0131 veya yan \u00fcr\u00fcnler \u00fcr\u00fcn performans\u0131n\u0131 d\u00fc\u015f\u00fcrebilir<\/td>\n<\/tr>\n<tr style=\"height: 26.25pt;\">\n<td class=\"et4\" style=\"height: 26.25pt; width: 114.75pt;\" width=\"153\" height=\"35\">Yo\u011fun \u0131\u015f\u0131k \u0131\u015f\u0131nlama y\u00f6ntemi<\/td>\n<td class=\"et5\" style=\"width: 207.00pt;\" width=\"276\">\u00dcr\u00fcn \u00fczerinde olumsuz etki yok<\/td>\n<td class=\"et5\" style=\"width: 222.00pt;\" width=\"296\">Ekipman maliyetlerini art\u0131r\u0131r<\/td>\n<\/tr>\n<tr style=\"height: 26.25pt;\">\n<td class=\"et4\" style=\"height: 26.25pt; width: 114.75pt;\" width=\"153\" height=\"35\">Thiol<\/td>\n<td class=\"et5\" style=\"width: 207.00pt;\" width=\"276\">Is\u0131 direncini art\u0131r\u0131r; su emilimini azalt\u0131r; yap\u0131\u015fmay\u0131 iyile\u015ftirir<\/td>\n<td class=\"et5\" style=\"width: 222.00pt;\" width=\"296\">Ho\u015f olmayan koku<\/td>\n<\/tr>\n<tr style=\"height: 26.25pt;\">\n<td class=\"et4\" style=\"height: 26.25pt; width: 114.75pt;\" width=\"153\" height=\"35\">Aminler<\/td>\n<td class=\"et5\" style=\"width: 207.00pt;\" width=\"276\">Ucuzdur; yap\u0131\u015fmay\u0131 iyile\u015ftirebilir<\/td>\n<td class=\"et5\" style=\"width: 222.00pt;\" width=\"296\">K\u00fcrlenme sonras\u0131 sararma sorunlar\u0131; neme kar\u015f\u0131 hassas<\/td>\n<\/tr>\n<tr style=\"height: 26.25pt;\">\n<td class=\"et4\" style=\"height: 26.25pt; width: 114.75pt;\" width=\"153\" height=\"35\">Eter<\/td>\n<td class=\"et5\" style=\"width: 207.00pt;\" width=\"276\">B\u00fcy\u00fck miktarlarda kullan\u0131labilir<\/td>\n<td class=\"et5\" style=\"width: 222.00pt;\" width=\"296\">Azalt\u0131lm\u0131\u015f s\u0131cakl\u0131k direnci; su direncini azaltabilir<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p><!-- lc-commercial-start --><\/p>\n<h2>A practical selection route for photoinitiator-related projects<\/h2>\n<p>When technical buyers or formulators screen photoinitiators, the most useful decision frame is usually cure quality plus application fit: which package cures reliably, keeps appearance acceptable, and still works under the lamp, film thickness, and substrate conditions of the actual process.<\/p>\n<ul>\n<li><strong>Match the package to the lamp first:<\/strong> mercury lamps, UV LEDs, and visible-light systems can rank the same photoinitiators very differently.<\/li>\n<li><strong>Check depth cure and surface cure separately:<\/strong> a film that feels dry on top can still be weak underneath.<\/li>\n<li><strong>Balance yellowing with reactivity:<\/strong> the strongest deep-cure route is not always the best commercial choice if color or migration risk becomes unacceptable.<\/li>\n<li><strong>Use the final formula as the benchmark:<\/strong> pigment load, monomer package, and film thickness can all change the apparent ranking of the same initiator.<\/li>\n<\/ul>\n<h3>Recommended product references<\/h3>\n<ul>\n<li><strong><a href=\"https:\/\/longchangchemical.com\/tr\/product\/photoinitiator-tpo-l-cas-84434-11-7\/\">CHLUMINIT TPO-L<\/a>:<\/strong> A strong low-yellowing reference for LED-oriented UV systems.<\/li>\n<li><strong><a href=\"https:\/\/longchangchemical.com\/tr\/product\/photoinitiator-819-irgacure-819-cas-162881-26-7\/\">CHLUMINIT 819<\/a>:<\/strong> Useful when a formulation needs stronger absorption and deeper cure support.<\/li>\n<li><strong><a href=\"https:\/\/longchangchemical.com\/tr\/product\/photoinitiator-184-cas-947-19-3\/\">CHLUMINIT 184<\/a>:<\/strong> A classic free-radical benchmark for fast surface cure in many UV systems.<\/li>\n<\/ul>\n<h3>FAQ for buyers and formulators<\/h3>\n<p><strong>Why are blended photoinitiator packages so common?<\/strong><br \/>Because one product may control yellowing or lamp fit well while another improves cure depth or line-speed performance, so the full package is often stronger than any single grade.<\/p>\n<p><strong>Should incomplete cure always be solved by adding more initiator?<\/strong><br \/>Not automatically. The real limitation may be the lamp, film thickness, pigment shading, or the rest of the reactive system rather than simple under-dosage.<\/p>\n<p><!-- lc-commercial-end --><\/p>","protected":false},"excerpt":{"rendered":"<p>Oxygen blocking is also called oxygen inhibition. Due to the high concentration of oxygen in the surface layer, the oxygen inhibition will lead to the lower layer has been cured,<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[114],"tags":[],"class_list":["post-5698","post","type-post","status-publish","format-standard","hentry","category-catalysts-chemical-auxiliary-agents"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.3.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>How to inhibit oxygen blocking? - Longchang Chemical<\/title>\n<meta name=\"description\" content=\"Oxygen blocking is also called oxygen inhibition. 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