{"id":5342,"date":"2022-07-01T12:12:25","date_gmt":"2022-07-01T12:12:25","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=5342"},"modified":"2026-04-28T10:42:02","modified_gmt":"2026-04-28T10:42:02","slug":"how-to-reduce-the-shrinkage-of-uv-glue","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/tr\/how-to-reduce-the-shrinkage-of-uv-glue\/","title":{"rendered":"UV yap\u0131\u015ft\u0131r\u0131c\u0131n\u0131n b\u00fcz\u00fclmesi nas\u0131l azalt\u0131l\u0131r? Y\u00f6ntemler nelerdir?"},"content":{"rendered":"<h1><strong>UV yap\u0131\u015ft\u0131r\u0131c\u0131n\u0131n b\u00fcz\u00fclmesi nas\u0131l azalt\u0131l\u0131r? Y\u00f6ntemler nelerdir?<\/strong><\/h1>\n<p><!-- lc-qa-start --><\/p>\n<p><strong>H\u0131zl\u0131 cevap:<\/strong> \u00c7o\u011fu UV sisteminde, foto ba\u015f la t\u0131c \u0131 lar dalga boyu uyumu, tam k\u00fcrlenme, renk kontrol\u00fc ve hat h\u0131z\u0131 aras\u0131ndaki denge ile se\u00e7ilir. Al\u0131c\u0131lar genellikle tek bir izole \u00fcr\u00fcn yerine harmanlanm\u0131\u015f bir paketi kar\u015f\u0131la\u015ft\u0131r\u0131r.<\/p>\n<p><!-- lc-qa-end --><\/p>\n<p>UV yap\u0131\u015ft\u0131r\u0131c\u0131n\u0131n k\u00fcrlenme s\u00fcrecinde bir jelle\u015fme s\u00fcreci vard\u0131r. Jelle\u015fmeden \u00f6nce, b\u00fcz\u00fclmeye ra\u011fmen sistem hala ak\u0131\u015fkanken, jelle\u015fmeden sonra molek\u00fcler hareket engellenir ve daha fazla k\u00fcrlenme reaksiyonu b\u00fcz\u00fclme stresinin ana nedenidir. Bu nedenle, b\u00fcz\u00fclme stresi t\u00fcm k\u00fcrleme s\u00fcrecinin hacimsel b\u00fcz\u00fclmesiyle orant\u0131l\u0131 de\u011fildir. Aksine, jelle\u015fmeden sonraki hacimsel b\u00fcz\u00fclmeye ba\u011fl\u0131d\u0131r. Reaktanlar\u0131n fonksiyonelli\u011fi ne kadar y\u00fcksek olursa, jelle\u015fme ger\u00e7ekle\u015fti\u011finde fonksiyonel gruplar\u0131n reaksiyon derecesi o kadar d\u00fc\u015f\u00fck olur. Bu nedenle, y\u00fcksek derecede i\u015flevselli\u011fe sahip bir reaksiyon sistemi, k\u00fcrlemeden sonra daha y\u00fcksek bir b\u00fcz\u00fclme gerilimi \u00fcretecektir.<\/p>\n<p>UV yap\u0131\u015ft\u0131r\u0131c\u0131n\u0131n b\u00fcz\u00fclmesini azaltman\u0131n yollar\u0131<\/p>\n<p>1. D\u00fc\u015f\u00fck b\u00fcz\u00fclmeli monomer ve oligomerlerin kullan\u0131m\u0131nda UV tutkal form\u00fclasyonu<\/p>\n<p>In the UV glue formula, the use of low viscosity acrylate oligomer and less dilution monomer is also an effective way to reduce the shrinkage rate. Formulators often compare <a href=\"https:\/\/longchangchemical.com\/tr\/product\/iboa-monomer-cas-5888-33-5\/\">IBOA Monomer<\/a> for lower stress with <a href=\"https:\/\/longchangchemical.com\/tr\/product\/tmpta-cas-15625-89-5\/\">TMPTA Monomer<\/a> for higher reactivity and crosslink density.<\/p>\n<p>2. UV tutkal katk\u0131l\u0131 polimer veya inorganik dolgu<\/p>\n<p>Polimer ekleme y\u00f6nteminde, yeni olu\u015fturulan sistem ve \u00f6nceden eklenmi\u015f polimerler aras\u0131nda bazen k\u00fcrleme i\u015flemi s\u0131ras\u0131nda meydana gelen faz ayr\u0131m\u0131, hacim b\u00fcz\u00fclmesinin bir k\u0131sm\u0131n\u0131 da telafi edebilir. Ancak bu faz ayr\u0131m\u0131n\u0131n dezavantaj\u0131, k\u00fcrlenmi\u015f \u00fcr\u00fcn\u00fcn \u015feffafl\u0131\u011f\u0131n\u0131 azaltmas\u0131d\u0131r. Serbest radikal polimerizasyon sistemine polivinil asetat, polivinil asetal, polyester ve di\u011fer termoplastik polimerlerin eklenmesinin hacim b\u00fcz\u00fclmesinde \u00f6nemli bir azalmaya neden olabilece\u011fi bildirilmi\u015ftir.<\/p>\n<p>3. Katyonik veya hibrit k\u00fcrleme y\u00f6nteminin kullan\u0131lmas\u0131<\/p>\n<p>Katyonik UV yap\u0131\u015ft\u0131r\u0131c\u0131, fotoba\u015flat\u0131c\u0131 olarak iyon tuzlar\u0131 ile epoksi re\u00e7ine ve vinil eter monomerlerini kullan\u0131r. Epoksi re\u00e7inenin katyonik k\u00fcrleme reaksiyonunun b\u00fcz\u00fclme oran\u0131, serbest radikal reaksiyonundan \u00e7ok daha d\u00fc\u015f\u00fckt\u00fcr, bu nedenle k\u00fcrleme b\u00fcz\u00fclme oran\u0131 katyonik form\u00fcl kullan\u0131larak azalt\u0131labilir.<\/p>\n<p>Hibrit UV yap\u0131\u015ft\u0131r\u0131c\u0131, genellikle kar\u0131\u015f\u0131k akrilat ve epoksi bile\u015fikleri \u015feklinde, serbest radikal ve katyonik tipte kar\u0131\u015f\u0131k bir sistemdir. Bu hibrit UV k\u00fcrleme sistemi, fotoba\u015flat\u0131ld\u0131\u011f\u0131nda ba\u015flatma verimlili\u011fini art\u0131rabilir, her ikisinin avantajlar\u0131n\u0131 tam olarak kullanabilir, hacim b\u00fcz\u00fclmesini azaltabilir ve di\u011fer \u00f6zelliklerde iyi sinerjik etkilere sahip olabilir.<\/p>\n<p>Buna ek olarak, proses gereksinimlerine g\u00f6re, UV ve \u0131s\u0131 ile k\u00fcrleme veya anaerobik k\u00fcrleme bile\u015fi\u011fi y\u00f6ntemi gibi UV ve di\u011fer k\u00fcrleme y\u00f6ntemleri de k\u00fcrleme b\u00fcz\u00fclmesini azaltabilir.<\/p>\n<p>4. \u015ei\u015fen monomer ekleme<\/p>\n<p>Epoksi re\u00e7ine katyonik polimerizasyon reaksiyonundan zaten bilinmektedir, a\u00e7\u0131k halka polimerizasyon reaksiyonu, polimerizasyon reaksiyonu hacim b\u00fcz\u00fclme oran\u0131n\u0131n eklenmesinden daha k\u00fc\u00e7\u00fckt\u00fcr. Monosiklik monomerler i\u00e7in, bir kovalent ba\u011f mesafesine d\u00f6n\u00fc\u015ft\u00fcr\u00fclen her van der Waals mesafesi i\u00e7in, bir van der Waals mesafesine d\u00f6n\u00fc\u015ft\u00fcr\u00fclen bir kovalent mesafe vard\u0131r. Ortaya \u00e7\u0131kan b\u00fcz\u00fclme ve \u015fi\u015fme k\u0131smen dengelenebilir. Daha ileri \u00e7al\u0131\u015fmalar, halka a\u00e7ma polimerizasyon reaksiyonunun hacim daralmas\u0131n\u0131n boyutunun halkan\u0131n boyutuyla ili\u015fkili oldu\u011funu ortaya koymu\u015ftur. Halkan\u0131n boyutu artt\u0131k\u00e7a, kovalent ba\u011flar\u0131 a\u00e7an karbon ve oksijen atomlar\u0131 aras\u0131ndaki mesafe van der Waals mesafesine yakla\u015f\u0131r ve b\u00f6ylece hacim daralmas\u0131 azal\u0131r. \u015eu anda, spiro halka tipi monomerin maliyeti \u00e7ok y\u00fcksektir, bu nedenle pratik uygulamas\u0131 hala \u00e7ok azd\u0131r, ancak UV tutkal\u0131n\u0131n b\u00fcz\u00fclmesini ortadan kald\u0131rmak i\u00e7in umut verici bir y\u00f6ntemdir.<\/p>\n<p><!-- lc-commercial-start --><\/p>\n<h2>Form\u00fclat\u00f6rler bu foto ba\u015flat\u0131c\u0131 konusunu genellikle nas\u0131l de\u011ferlendirirler?<\/h2>\n<p>Teknik al\u0131c\u0131lar veya form\u00fclat\u00f6rler foto ba\u015flatanlar\u0131 incelerken, en kullan\u0131\u015fl\u0131 karar \u00e7er\u00e7evesi genellikle k\u00fcr kalitesi art\u0131 uygulama uygunlu\u011fudur: hangi paket g\u00fcvenilir bir \u015fekilde k\u00fcrlenir, g\u00f6r\u00fcn\u00fcm\u00fc kabul edilebilir tutar ve yine de ger\u00e7ek s\u00fcrecin lamba, film kal\u0131nl\u0131\u011f\u0131 ve alt tabaka ko\u015fullar\u0131 alt\u0131nda \u00e7al\u0131\u015f\u0131r.<\/p>\n<ul>\n<li><strong>\u00d6nce paketi lambaya e\u015fle\u015ftirin:<\/strong> C\u0131va lambalar\u0131, UV LED'ler ve g\u00f6r\u00fcn\u00fcr \u0131\u015f\u0131k sistemleri ayn\u0131 foto ba\u015flatanlar\u0131 \u00e7ok farkl\u0131 s\u0131ralayabilir.<\/li>\n<li><strong>Derin k\u00fcrle\u015fmeyi ve y\u00fczey k\u00fcrle\u015fmesini ayr\u0131 ayr\u0131 kontrol edin:<\/strong> \u00dcst\u00fc kuru hissettiren bir film, alt\u0131nda zay\u0131f olabilir.<\/li>\n<li><strong>Sar\u0131la\u015fmay\u0131 reaktiflikle dengeleyin:<\/strong> En g\u00fc\u00e7l\u00fc derin k\u00fcrlenme rotas\u0131, renk veya migrasyon riski kabul edilemez hale geldi\u011finde her zaman en iyi ticari tercih de\u011fildir.<\/li>\n<li><strong>Son form\u00fcl\u00fc referans al\u0131n:<\/strong> Pigment y\u00fck\u00fc, monomer paketi ve film kal\u0131nl\u0131\u011f\u0131, ayn\u0131 ba\u015flat\u0131c\u0131n\u0131n g\u00f6r\u00fcnen s\u0131ralamas\u0131n\u0131 de\u011fi\u015ftirebilir.<\/li>\n<\/ul>\n<h3>\u00d6nerilen \u00fcr\u00fcn referanslar\u0131<\/h3>\n<ul>\n<li><strong><a href=\"https:\/\/longchangchemical.com\/tr\/product\/photoinitiator-tpo-l-cas-84434-11-7\/\">CHLUMINIT TPO-L<\/a>:<\/strong> LED odakl\u0131 UV sistemleri i\u00e7in g\u00fc\u00e7l\u00fc, d\u00fc\u015f\u00fck sararma oran\u0131na sahip bir referans.<\/li>\n<li><strong><a href=\"https:\/\/longchangchemical.com\/tr\/product\/photoinitiator-819-irgacure-819-cas-162881-26-7\/\">CHLUMINIT 819<\/a>:<\/strong> Form\u00fclasyonun daha g\u00fc\u00e7l\u00fc emilim ve daha derin k\u00fcr deste\u011fine ihtiya\u00e7 duydu\u011funda kullan\u0131\u015fl\u0131d\u0131r.<\/li>\n<li><strong><a href=\"https:\/\/longchangchemical.com\/tr\/product\/iboa-monomer-cas-5888-33-5\/\">CHLUMICRYL IBOA<\/a>:<\/strong> Sertlik ve iyi ak\u0131\u015fkanl\u0131\u011f\u0131n her ikisinin de \u00f6nemli oldu\u011fu durumlarda g\u00fc\u00e7l\u00fc, d\u00fc\u015f\u00fck viskoziteli bir monomer referans\u0131.<\/li>\n<li><strong><a href=\"https:\/\/longchangchemical.com\/tr\/product\/tmpta-cas-15625-89-5\/\">CHLUMICRYL TMPTA<\/a>:<\/strong> Daha g\u00fc\u00e7l\u00fc \u00e7apraz ba\u011f yo\u011funlu\u011fu gerekti\u011finde standart bir reaktif monomer referans noktas\u0131.<\/li>\n<\/ul>\n<h3>Al\u0131c\u0131lar ve form\u00fclat\u00f6rler i\u00e7in SSS<\/h3>\n<p><strong>Kar\u0131\u015f\u0131k foto ba\u015flat\u0131c\u0131 paketleri neden bu kadar yayg\u0131n?<\/strong><br \/>\u00c7\u00fcnk\u00fc bir \u00fcr\u00fcn sararmay\u0131 engelleyebilir veya lamba uyumunu iyile\u015ftirebilirken, di\u011feri k\u00fcr derinli\u011fini veya hat h\u0131z\u0131 performans\u0131n\u0131 art\u0131rabilir, bu nedenle tam paket genellikle tek bir dereceden daha g\u00fc\u00e7l\u00fcd\u00fcr.<\/p>\n<p><strong>Tamamlanmam\u0131\u015f k\u00fcr her zaman daha fazla ba\u015flat\u0131c\u0131 eklenerek mi \u00e7\u00f6z\u00fclmelidir?<\/strong><br \/>Otomatik olarak de\u011fil. Ger\u00e7ek s\u0131n\u0131rlama, basit dozaj eksikli\u011finden ziyade lamba, film kal\u0131nl\u0131\u011f\u0131, pigment g\u00f6lgelendirmesi veya reaktif sistemin geri kalan\u0131 olabilir.<\/p>\n<p><!-- lc-commercial-end --><\/p>\n<h2><strong><b>\u015eimdi Bize Ula\u015f\u0131n!<\/b><\/strong><\/h2>\n<h4><strong><b>E\u011fer <\/b><\/strong><strong><b>Fiyat veya COA, MSDS veya TDS'ye ihtiyac\u0131n\u0131z varsa, l\u00fctfen <\/b><\/strong><strong><b>A\u015fa\u011f\u0131daki formu doldurun ve genellikle 24 saat i\u00e7inde sizinle ileti\u015fime ge\u00e7ece\u011fimizi belirtin. Bana e-posta da g\u00f6nderebilirsiniz <span style=\"color: #0000ff;\"><a style=\"color: #0000ff;\" href=\"mailto:info@longchangchemical.com\">info@longchangchemical.com<\/a><\/span> \u00c7al\u0131\u015fma saatleri i\u00e7inde (8:30 - 6:00 UTC+8 Pzt.~Sat.) veya h\u0131zl\u0131 yan\u0131t almak i\u00e7in web sitesi canl\u0131 sohbetini kullan\u0131n.<\/b><\/strong><\/h4>","protected":false},"excerpt":{"rendered":"<p>In the curing process of UV adhesive there is a gelation process. Before gelation, the system is still fluid despite the shrinkage, while after gelation, the molecular movement is hindered<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[114],"tags":[],"class_list":["post-5342","post","type-post","status-publish","format-standard","hentry","category-catalysts-chemical-auxiliary-agents"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.3.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>How to reduce the shrinkage of UV glue? What are the methods? - Longchang chemical<\/title>\n<meta name=\"description\" content=\"In the curing process of UV adhesive there is a gelation process. 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