{"id":4990,"date":"2022-01-17T09:10:53","date_gmt":"2022-01-17T09:10:53","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=4990"},"modified":"2024-12-11T15:26:03","modified_gmt":"2024-12-11T15:26:03","slug":"relationship-between-the-odor-and-structure-of-uv-monomers","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/pt\/relationship-between-the-odor-and-structure-of-uv-monomers\/","title":{"rendered":"Qual \u00e9 a rela\u00e7\u00e3o entre o odor e a estrutura dos mon\u00f4meros UV?"},"content":{"rendered":"

Qual \u00e9 a rela\u00e7\u00e3o entre o odor e a estrutura dos mon\u00f4meros UV?<\/strong><\/h1>\r\n

O acrilato \u00e9 amplamente utilizado na fabrica\u00e7\u00e3o de v\u00e1rios materiais polim\u00e9ricos, principalmente devido \u00e0 sua flexibilidade em baixas temperaturas, resist\u00eancia ao calor, resist\u00eancia ao envelhecimento, alta transpar\u00eancia e estabilidade de cor. Essas propriedades permitem que ele seja usado em uma ampla gama de aplica\u00e7\u00f5es, incluindo pl\u00e1sticos, vernizes para pisos, revestimentos, t\u00eaxteis, tintas e adesivos. O tipo e a quantidade de mon\u00f4mero de acrilato usado t\u00eam um impacto significativo sobre as propriedades do produto final, incluindo a temperatura de transi\u00e7\u00e3o v\u00edtrea, a viscosidade, a dureza e a durabilidade. A copolimeriza\u00e7\u00e3o com mon\u00f4meros com grupos funcionais de hidroxila, metila ou carboxila pode resultar em mais pol\u00edmeros adequados para diferentes aplica\u00e7\u00f5es.<\/p>\r\n\r\n\r\n\r\n

Os materiais obtidos pela polimeriza\u00e7\u00e3o de mon\u00f4meros de acrilato s\u00e3o amplamente utilizados na ind\u00fastria, mas os mon\u00f4meros residuais s\u00e3o frequentemente encontrados nos materiais polimerizados. Esses mon\u00f4meros residuais podem n\u00e3o apenas causar problemas como irrita\u00e7\u00e3o da pele, mas tamb\u00e9m causar um odor desagrad\u00e1vel no produto final devido ao odor desagrad\u00e1vel desses pr\u00f3prios mon\u00f4meros.<\/p>\r\n\r\n\r\n\r\n

O sistema olfativo humano pode perceber concentra\u00e7\u00f5es muito baixas de mon\u00f4meros de acrilato. Para muitos materiais de pol\u00edmero de acrilato, a maior parte do odor do produto vem dos mon\u00f4meros de acrilato. Mon\u00f4meros diferentes t\u00eam odores diferentes, mas qual \u00e9 a rela\u00e7\u00e3o entre a estrutura do mon\u00f4mero e o odor?<\/p>\r\n\r\n\r\n\r\n

\"\"\r\n
Figura 1 Estruturas qu\u00edmicas dos mon\u00f4meros de acrilato estudados (comerciais e sint\u00e9ticos)<\/figcaption>\r\n<\/figure>\r\n\r\n\r\n\r\n

Um total de 20 odores individuais foi testado para o estudo. Esses mon\u00f4meros incluem mon\u00f4meros comerciais e sintetizados em laborat\u00f3rio. Os testes mostraram que os odores desses mon\u00f4meros podem ser classificados como tendo odores de enxofre, g\u00e1s mais leve, ger\u00e2nio e cogumelo.<\/p>\r\n\r\n\r\n\r\n

O diacrilato de 1,2-propanodiol (n\u00ba 16), o acrilato de metila (n\u00ba 1), o acrilato de etila (n\u00ba 2) e o acrilato de propila (n\u00ba 3) s\u00e3o descritos principalmente como odores de enxofre e alho. Al\u00e9m disso, as duas \u00faltimas subst\u00e2ncias tamb\u00e9m foram descritas como tendo um odor de g\u00e1s mais leve, e o acrilato de etila e o diacrilato de 1,2-propilenoglicol tinham a impress\u00e3o de um pequeno odor de cola. O acrilato de vinila (n\u00ba 5) e o acrilato de propileno (n\u00ba 6) foram descritos como odores de combust\u00edvel gasoso, o acrilato de 1-hidroxi-isopropila (n\u00ba 10) e o acrilato de 2-hidroxin-propila (n\u00ba 12) foram descritos como cheiro de ger\u00e2nio e g\u00e1s mais leve. 4), acrilato de 3-(Z)pentenila (n\u00ba 7), acrilato de sec-butila (ger\u00e2nio, sabor de cogumelo; n\u00ba 8), acrilato de 2-hidroxietila (n\u00ba 11), acrilato de 4-metilpentila (cogumelo, frutado; n\u00ba 14) e diacrilato de etilenoglicol (n\u00ba 15) foram descritos como odores de cogumelo. O acrilato de isobutila (n\u00ba 9), o acrilato de 2-etilhexila (n\u00ba 13), o acrilato de ciclopentila (n\u00ba 17) e o acrilato de ciclohexano (n\u00ba 18) s\u00e3o descritos como cheiro de cenoura e cheiro de ger\u00e2nio. O acrilato de 2-metoxifenila (n\u00ba 19) tem cheiro de ger\u00e2nio e presunto, enquanto seu is\u00f4mero acrilato de 4-metoxifenila (n\u00ba 20) \u00e9 descrito como cheiro de anis e anis.<\/p>\r\n\r\n\r\n\r\n

Os limiares de odor dos mon\u00f4meros testados apresentaram grandes diferen\u00e7as. O limiar de odor aqui se refere \u00e0 concentra\u00e7\u00e3o da subst\u00e2ncia que produz o menor est\u00edmulo \u00e0 percep\u00e7\u00e3o humana do odor, tamb\u00e9m conhecido como limiar olfativo. Quanto maior o limiar de odor, menor o odor. Com base nos resultados experimentais, pode-se observar que o limiar de odor \u00e9 mais afetado pelos grupos funcionais do que pelo comprimento da cadeia. Entre os 20 mon\u00f4meros testados, os limiares de odor mais baixos foram o acrilato de 2-metoxifenila (n\u00ba 19) e o acrilato de sec-butila (n\u00ba 8), com limiares de odor de 0,068 ng\/Lair e 0,068 ng\/Lair, respectivamente. 0,073 ng\/Lair. O acrilato de 2-hidroxi-n-propila (n\u00ba 12) e o acrilato de 2-hidroxietila (n\u00ba 11) apresentaram os limiares de odor mais altos, 106 ng\/Lair e 178 ng\/Lair, respectivamente, para acr\u00edlico - 5 e 9 vezes mais do que o \u00e9ster de 2-etilhexila (n\u00ba 13).<\/p>\r\n

 <\/p>\r\n

 <\/p>\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n
Poliol\/Polimercaptana<\/strong><\/td>\r\n\u00a0<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DMES<\/a><\/span><\/td>\r\nSulfeto de bis(2-mercaptoetil)<\/td>\r\n3570-55-6<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DMPT<\/a><\/span><\/td>\r\nTHIOCURE DMPT<\/td>\r\n131538-00-6<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de PETMP<\/a><\/span><\/td>\r\nTETRA(3-MERCAPTOPROPIONATO) DE PENTAERITRITOL<\/td>\r\n7575-23-7<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero PM839<\/a><\/span><\/td>\r\nPolioxi(metil-1,2-etanodil)<\/td>\r\n72244-98-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero monofuncional<\/strong><\/td>\r\n\u00a0<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero HEMA<\/a><\/span><\/td>\r\nMetacrilato de 2-hidroxietil<\/td>\r\n868-77-9<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero HPMA<\/a><\/span><\/td>\r\nMetacrilato de 2-hidroxipropila<\/td>\r\n27813-02-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero THFA<\/a><\/span><\/td>\r\nAcrilato de tetrahidrofurfurila<\/td>\r\n2399-48-6<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero HDCPA<\/a><\/span><\/td>\r\nAcrilato de diciclopentenila hidrogenado<\/td>\r\n79637-74-4<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DCPMA<\/a><\/span><\/td>\r\nMetacrilato de di-hidrodiciclopentadienila<\/td>\r\n30798-39-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DCPA<\/a><\/span><\/td>\r\nAcrilato de di-hidrodiciclopentadienila<\/td>\r\n12542-30-2<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DCPEMA<\/a><\/span><\/td>\r\nMetacrilato de diciclopenteniloxietil<\/td>\r\n68586-19-6<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DCPEOA<\/a><\/span><\/td>\r\nAcrilato de diciclopenteniloxietil<\/td>\r\n65983-31-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero NP-4EA<\/a><\/span><\/td>\r\n(4) nonilfenol etoxilado<\/td>\r\n50974-47-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero LA<\/td>\r\nAcrilato de laurila \/ Acrilato de dodecila<\/td>\r\n2156-97-0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero THFMA<\/a><\/span><\/td>\r\nMetacrilato de tetrahidrofurfurila<\/td>\r\n2455-24-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de PHEA<\/span><\/a><\/td>\r\nACRILATO DE 2-FENOXIETIL<\/td>\r\n48145-04-6<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero LMA<\/a><\/span><\/td>\r\nMetacrilato de lauril<\/td>\r\n142-90-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero IDA<\/a><\/span><\/td>\r\nAcrilato de isodecila<\/td>\r\n1330-61-6<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero IBOMA<\/a><\/span><\/td>\r\nMetacrilato de isobornila<\/td>\r\n7534-94-3<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero IBOA<\/a><\/span><\/td>\r\nAcrilato de isobornila<\/td>\r\n5888-33-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EOEOEA<\/a><\/span><\/td>\r\n2-(2-Etoxietoxi)acrilato de etila<\/td>\r\n7328-17-8<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero multifuncional<\/strong><\/td>\r\n\u00a0<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
DPHA Mon\u00f4mero<\/a><\/span><\/td>\r\nDipentaeritritol hexaacrilato<\/td>\r\n29570-58-9<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DI-TMPTA<\/a><\/span><\/td>\r\nTETRAACRILATO DE DI(TRIMETILOLPROPANO)<\/td>\r\n94108-97-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de acrilamida<\/strong><\/td>\r\n\u00a0<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero ACMO<\/a><\/span><\/td>\r\n4-acriloilmorfolina<\/td>\r\n5117-12-4<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero di-funcional<\/strong><\/td>\r\n\u00a0<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero PEGDMA<\/a><\/span><\/td>\r\nDimetacrilato de poli(etilenoglicol)<\/td>\r\n25852-47-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero TPGDA<\/a><\/span><\/td>\r\nDiacrilato de tripropilenoglicol<\/td>\r\n42978-66-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero TEGDMA<\/a><\/span><\/td>\r\nDimetacrilato de trietilenoglicol<\/td>\r\n109-16-0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero PO2-NPGDA<\/span><\/a><\/td>\r\nDiacrilato de neopentileno glicol propoxilado<\/td>\r\n84170-74-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de PEGDA<\/a><\/span><\/td>\r\nDiacrilato de polietileno glicol<\/td>\r\n26570-48-9<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero PDDA<\/a><\/span><\/td>\r\nFtalato de diacrilato de dietilenoglicol<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero NPGDA<\/a><\/span><\/td>\r\nDiacrilato de neopentil glicol<\/td>\r\n2223-82-7<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero HDDA<\/a><\/span><\/td>\r\nDiacrilato de hexametileno<\/td>\r\n13048-33-4<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EO4-BPADA<\/span><\/a><\/td>\r\nDIACRILATO DE BISFENOL A ETOXILADO (4)<\/td>\r\n64401-02-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EO10-BPADA<\/a><\/span><\/td>\r\nDIACRILATO DE BISFENOL A ETOXILADO (10)<\/td>\r\n64401-02-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EGDMA<\/a><\/span><\/td>\r\nDimetacrilato de etilenoglicol<\/td>\r\n97-90-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DPGDA<\/a><\/span><\/td>\r\nDienoato de Dipropileno Glicol<\/td>\r\n57472-68-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero Bis-GMA<\/a><\/span><\/td>\r\nBisfenol A Metacrilato de glicidila<\/td>\r\n1565-94-2<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero trifuncional<\/strong><\/td>\r\n\u00a0<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero TMPTMA<\/a><\/span><\/td>\r\nTrimetacrilato de trimetilolpropano<\/td>\r\n3290-92-4<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de TMPTA<\/a><\/span><\/td>\r\nTriacrilato de trimetilolpropano<\/td>\r\n15625-89-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero PETA<\/a><\/span><\/td>\r\nTriacrilato de pentaeritritol<\/td>\r\n3524-68-3<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de GPTA ( G3POTA )<\/a><\/span><\/td>\r\nTRIACRILATO DE GLICERIL PROPOXI<\/td>\r\n52408-84-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EO3-TMPTA<\/a><\/span><\/td>\r\nTriacrilato de trimetilolpropano etoxilado<\/td>\r\n28961-43-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero fotorresistente<\/strong><\/td>\r\n\u00a0<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero IPAMA<\/a><\/span><\/td>\r\nMetacrilato de 2-isopropil-2-adamantila<\/td>\r\n297156-50-4<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero ECPMA<\/a><\/span><\/td>\r\nMetacrilato de 1-etilciclopentila<\/td>\r\n266308-58-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero ADAMA<\/a><\/span><\/td>\r\nMetacrilato de 1-amant\u00edlico<\/td>\r\n16887-36-8<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de metacrilatos<\/strong><\/td>\r\n\u00a0<\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero TBAEMA<\/a><\/span><\/td>\r\nMetacrilato de 2-(terc-butilamino)etila<\/td>\r\n3775-90-4<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero NBMA<\/a><\/span><\/td>\r\nMetacrilato de n-butilo<\/td>\r\n97-88-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero MEMA<\/a><\/span><\/td>\r\nMetacrilato de 2-metoxietil<\/td>\r\n6976-93-8<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero i-BMA<\/a><\/span><\/td>\r\nMetacrilato de isobutilo<\/td>\r\n97-86-9<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EHMA<\/a><\/span><\/td>\r\nMetacrilato de 2-etil-hexila<\/td>\r\n688-84-6<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EGDMP<\/a><\/span><\/td>\r\nBis(3-mercaptopropionato) de etilenoglicol<\/td>\r\n22504-50-3<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EEMA<\/a><\/span><\/td>\r\n2-etoxietil 2-metilprop-2-enoato<\/td>\r\n2370-63-0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DMAEMA<\/a><\/span><\/td>\r\nN,M-Dimetilaminoetil metacrilato<\/td>\r\n2867-47-2<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DEAM<\/a><\/span><\/td>\r\nMetacrilato de dietilaminoetila<\/td>\r\n105-16-8<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero CHMA<\/a><\/span><\/td>\r\nMetacrilato de ciclohexila<\/td>\r\n101-43-9<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero BZMA<\/a><\/span><\/td>\r\nMetacrilato de benzila<\/td>\r\n2495-37-6<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero BDDMP<\/a><\/span><\/td>\r\nDi(3-mercaptopropionato) de 1,4-butanodiol<\/td>\r\n92140-97-1<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de BDDMA<\/a><\/span><\/td>\r\n1,4-Butanodioldimetacrilato<\/td>\r\n2082-81-7<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero AMA<\/a><\/span><\/td>\r\nMetacrilato de alila<\/td>\r\n96-05-9<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero AAEM<\/a><\/span><\/td>\r\nMetacrilato de acetilacetoxietil<\/td>\r\n21282-97-3<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de acrilatos<\/strong><\/td>\r\n\u00a0<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero de IBA<\/a><\/span><\/td>\r\nAcrilato de isobutilo<\/td>\r\n106-63-8<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero EMA<\/a><\/span><\/td>\r\nMetacrilato de etila<\/td>\r\n97-63-2<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DMAEA<\/a><\/span><\/td>\r\nAcrilato de dimetilaminoetila<\/td>\r\n2439-35-2<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero DEAEA<\/a><\/span><\/td>\r\n2-(dietilamino)etil prop-2-enoato<\/td>\r\n2426-54-2<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero CHA<\/a><\/span><\/td>\r\nciclohexil prop-2-enoato<\/td>\r\n3066-71-5<\/td>\r\n<\/tr>\r\n
Mon\u00f4mero BZA<\/a><\/span><\/td>\r\nprop-2-enoato de benzila<\/td>\r\n2495-35-4<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>\r\n

 <\/p>\r\n

Entre em contato conosco agora!<\/b><\/strong><\/p>\r\n

Se precisar de COA, MSDS ou TDS de mon\u00f4meros uv, preencha suas informa\u00e7\u00f5es de contato no formul\u00e1rio abaixo. Em geral, entraremos em contato em 24 horas. Voc\u00ea tamb\u00e9m pode me enviar um e-mail info@longchangchemical.com<\/a><\/span> durante o hor\u00e1rio comercial (das 8h30 \u00e0s 18h UTC+8 de segunda a s\u00e1bado) ou use o bate-papo ao vivo do site para obter uma resposta imediata.<\/b><\/strong><\/h4>","protected":false},"excerpt":{"rendered":"

Qual \u00e9 a rela\u00e7\u00e3o entre o odor e a estrutura dos mon\u00f4meros UV? O acrilato \u00e9 amplamente usado na fabrica\u00e7\u00e3o de v\u00e1rios materiais polim\u00e9ricos, principalmente por causa de sua flexibilidade em baixas temperaturas, resist\u00eancia ao calor, resist\u00eancia ao envelhecimento, alta transpar\u00eancia e estabilidade de cor. Essas propriedades permitem que ele seja usado em uma ampla gama de aplica\u00e7\u00f5es, incluindo pl\u00e1sticos, [...]<\/p>","protected":false},"author":1,"featured_media":4802,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[114],"tags":[],"class_list":["post-4990","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-catalysts-chemical-auxiliary-agents"],"yoast_head":"\nWhat is the relationship between the odor and structure of UV monomers? - Longchang Chemical<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/longchangchemical.com\/pt\/relationship-between-the-odor-and-structure-of-uv-monomers\/\" \/>\n<meta property=\"og:locale\" content=\"pt_BR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"What is the relationship between the odor and structure of UV monomers? - Longchang Chemical\" \/>\n<meta property=\"og:description\" content=\"What is the relationship between the odor and structure of UV monomers? 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