{"id":4883,"date":"2021-12-07T14:27:06","date_gmt":"2021-12-07T14:27:06","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=4883"},"modified":"2026-08-25T09:30:57","modified_gmt":"2026-08-25T09:30:57","slug":"how-to-choose-the-correct-crosslinking-agent","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/pt\/how-to-choose-the-correct-crosslinking-agent\/","title":{"rendered":"How to Choose a Crosslinking Agent: Chemistry & Testing"},"content":{"rendered":"

Resposta r\u00e1pida:<\/strong> A crosslinking agent must match the polymer’s reactive groups and the intended cure mechanism. Compare stoichiometry, activation temperature, pot life, network density, compatibility, by-products, exposure controls and final mechanical or chemical-resistance targets.<\/p>\n\n\n

Use a peroxide crosslinker as one defined route<\/h2>\n

O BIPB 96 organic peroxide crosslinker<\/a> page is a relevant reference for peroxide-cured rubber and polymer systems. It is not a universal coating crosslinker; compare active content, decomposition behavior, scorch safety, cure conditions and final properties in the intended polymer.<\/p>\n

What is a crosslinking agent?<\/strong><\/h2>\n\n\n\n\n

1. Agente de reticula\u00e7\u00e3o refere-se a um tipo de agente auxiliar que melhora a efici\u00eancia da reticula\u00e7\u00e3o de per\u00f3xidos, a maioria dos quais s\u00e3o compostos com grupos funcionais poliinsaturados. A contribui\u00e7\u00e3o do agente auxiliar de reticula\u00e7\u00e3o para a efici\u00eancia da reticula\u00e7\u00e3o \u00e9 geralmente entendida como o fornecimento de uma concentra\u00e7\u00e3o mais alta de locais reativos, inibindo rea\u00e7\u00f5es colaterais, como a despropor\u00e7\u00e3o do radical do pol\u00edmero ou a cis\u00e3o da cadeia, e ajudando a formar mais liga\u00e7\u00f5es de reticula\u00e7\u00e3o.<\/p>\n\n\n\n

2. O efeito de uso espec\u00edfico do agente de reticula\u00e7\u00e3o n\u00e3o est\u00e1 relacionado apenas \u00e0 sua estrutura qu\u00edmica e \u00e0 quantidade adicionada, mas tamb\u00e9m a v\u00e1rias condi\u00e7\u00f5es, como o tipo de pol\u00edmero e o per\u00f3xido de reticula\u00e7\u00e3o.<\/p>\n\n\n\n

<\/p>\n\n\n\n

1. A influ\u00eancia do agente de reticula\u00e7\u00e3o nas propriedades f\u00edsicas
<\/h3>\n\n\n\n

O uso de auxiliares de reticula\u00e7\u00e3o ajuda a aumentar a densidade de reticula\u00e7\u00e3o. Em termos de propriedades f\u00edsicas, isso se manifesta como um aumento do m\u00f3dulo, da dureza e uma diminui\u00e7\u00e3o do alongamento na ruptura e da compress\u00e3o. Em alguns casos, ele tamb\u00e9m pode melhorar a resist\u00eancia \u00e0 tra\u00e7\u00e3o, a resist\u00eancia ao rasgo, a resist\u00eancia ao calor, a resist\u00eancia \u00e0 abras\u00e3o ou o desempenho din\u00e2mico.
O efeito do uso do agente reticulante auxiliar nas propriedades f\u00edsicas se manifesta principalmente nos seguintes aspectos: (Nem todas as propriedades podem ser obtidas ao mesmo tempo, e algumas propriedades podem ser obtidas com o uso de agentes auxiliares espec\u00edficos)<\/p>\n\n\n\n


Reduzir o conjunto de compress\u00e3o permanente;<\/p>\n\n\n\n

Aumentar a flexibilidade<\/p>\n\n\n\n

Aumentar o m\u00f3dulo<\/p>\n\n\n\n

Aumentar a dureza;<\/p>\n\n\n\n

Reduzem a viscosidade da borracha e melhoram o desempenho do processamento;<\/p>\n\n\n\n

Melhora a resist\u00eancia ao \u00f3leo;<\/p>\n\n\n\n

Melhora a resist\u00eancia ao envelhecimento por calor;<\/p>\n\n\n\n

Melhora a ades\u00e3o de produtos de borracha e metal;<\/p>\n\n\n\n

Aumente a velocidade de vulcaniza\u00e7\u00e3o;<\/p>\n\n\n\n

Reduzir a quantidade de per\u00f3xido;<\/p>\n\n\n\n

Aumenta a resist\u00eancia \u00e0 tra\u00e7\u00e3o;<\/p>\n\n\n\n

Melhora o desempenho de rasgo e rasgo a quente;<\/p>\n\n\n\n

Melhora o desempenho din\u00e2mico de flex\u00e3o;<\/p>\n\n\n\n

<\/p>\n\n\n\n

2. A influ\u00eancia da estrutura do agente de reticula\u00e7\u00e3o no desempenho do agente de reticula\u00e7\u00e3o
<\/h3>\n\n\n\n

A estrutura do agente de reticula\u00e7\u00e3o est\u00e1 intimamente relacionada ao desempenho do agente de reticula\u00e7\u00e3o. O tipo de grupo funcional do auxiliar de reticula\u00e7\u00e3o, o n\u00famero de grupos funcionais, a estrutura da ponte de liga\u00e7\u00e3o, a polaridade da mol\u00e9cula, o peso molecular etc. afetar\u00e3o o desempenho do auxiliar de reticula\u00e7\u00e3o.<\/p>\n\n\n\n

O tipo e o n\u00famero de grupos funcionais s\u00e3o os principais par\u00e2metros que afetam o desempenho de vulcaniza\u00e7\u00e3o do agente de reticula\u00e7\u00e3o, o que afeta diretamente a atividade do agente de reticula\u00e7\u00e3o, a solubilidade no pol\u00edmero e as propriedades f\u00edsicas do produto. Os agentes de reticula\u00e7\u00e3o comuns s\u00e3o, em sua maioria, aditivos bifuncionais e trifuncionais;<\/p>\n\n\n\n

A estrutura da liga\u00e7\u00e3o da ponte, que inclui a polaridade da liga\u00e7\u00e3o da ponte, o comprimento da liga\u00e7\u00e3o da ponte e a estrutura molecular. Embora a estrutura da liga\u00e7\u00e3o de ponte geralmente n\u00e3o tenha efeito direto sobre a atividade do agente de reticula\u00e7\u00e3o, ela pode afetar a efici\u00eancia do agente de reticula\u00e7\u00e3o, a solubilidade no pol\u00edmero e a for\u00e7a da liga\u00e7\u00e3o de reticula\u00e7\u00e3o, que tamb\u00e9m s\u00e3o par\u00e2metros muito importantes. \uff1b<\/p>\n\n\n\n

O peso molecular pode ter um impacto na efici\u00eancia do agente reticulante e tamb\u00e9m pode ser usado como um importante par\u00e2metro de avalia\u00e7\u00e3o da volatilidade do agente reticulante. Se o peso molecular for pequeno, a volatilidade poder\u00e1 ser alta;
A polaridade do agente reticulante auxiliar pode afetar diretamente sua solubilidade no pol\u00edmero e outros fatores, afetando assim a efici\u00eancia e o desempenho da vulcaniza\u00e7\u00e3o;<\/p>\n\n\n\n

3. Classifica\u00e7\u00e3o dos auxiliares de reticula\u00e7\u00e3o<\/h3>\n\n\n\n

De acordo com sua contribui\u00e7\u00e3o para a vulcaniza\u00e7\u00e3o, os auxiliares de reticula\u00e7\u00e3o podem ser divididos em duas categorias. Uma delas \u00e9 aumentar o grau de vulcaniza\u00e7\u00e3o e, ao mesmo tempo, aumentar a velocidade de vulcaniza\u00e7\u00e3o, o que tamb\u00e9m \u00e9 chamado de primeiro tipo de auxiliar de reticula\u00e7\u00e3o; a outra \u00e9 aumentar apenas o grau de vulcaniza\u00e7\u00e3o ou a densidade de reticula\u00e7\u00e3o sem aumentar a velocidade de vulcaniza\u00e7\u00e3o, tamb\u00e9m conhecida como o segundo tipo de agente de reticula\u00e7\u00e3o.<\/p>\n\n\n\n

<\/p>\n\n\n\n

Entre em contato conosco agora!<\/strong><\/h2>\n\n\n\n

Por favor, indique a fonte.<\/strong> Preencha suas informa\u00e7\u00f5es de contato no formul\u00e1rio abaixo. Normalmente, entraremos em contato dentro de 24 horas. Voc\u00ea tamb\u00e9m pode me enviar um e-mail info@longchangchemical.com<\/a> durante o hor\u00e1rio comercial (das 8h30 \u00e0s 18h UTC+8 de segunda a s\u00e1bado) ou use o bate-papo ao vivo do site para obter uma resposta imediata.<\/strong><\/h4>","protected":false},"excerpt":{"rendered":"

What is a crosslinking agent? 1. Co-crosslinking agent refers to a type of auxiliary agent that improves the crosslinking efficiency of peroxides, most of which are compounds with polyunsaturated functional<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[114],"tags":[],"class_list":["post-4883","post","type-post","status-publish","format-standard","hentry","category-catalysts-chemical-auxiliary-agents"],"yoast_head":"\nHow to Choose a Crosslinking Agent: Chemistry & Testing<\/title>\n<meta name=\"description\" content=\"Choose a crosslinking agent by reactive groups, cure mechanism, temperature, pot life, network density, safety, compatibility and final performance testing.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" 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