{"id":5596,"date":"2022-09-23T08:37:38","date_gmt":"2022-09-23T08:37:38","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=5596"},"modified":"2022-09-23T08:37:38","modified_gmt":"2022-09-23T08:37:38","slug":"uv-oligomers-used-in-light-curing-coatings","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/hu\/uv-oligomers-used-in-light-curing-coatings\/","title":{"rendered":"F\u00e9nyre kem\u00e9nyed\u0151 bevonatokban haszn\u00e1lt UV oligomerek"},"content":{"rendered":"

F\u00e9nyre kem\u00e9nyed\u0151 bevonatokban haszn\u00e1lt UV oligomerek<\/strong><\/h1>\n

F\u00e9nykem\u00e9nyed\u0151 bevonatok haszn\u00e1lt oligomer is ismert, mint prepolimer, amely egy kis molekulat\u00f6meg\u0171, jellemz\u0151i a polimeriz\u00e1ci\u00f3s csoportok, viszkozit\u00e1s, a f\u0151 test f\u00e9nykem\u00e9nyed\u0151 bevonatok film. A f\u00e9nykem\u00e9nyed\u00e9s a tel\u00edtetlen molekul\u00e1k k\u00f6z\u00f6tti polimeriz\u00e1ci\u00f3s reakci\u00f3, az inici\u00e1tor ind\u00edt\u00f3 mechanizmusa szerint, vannak szabad gy\u00f6k\u00f6s polimeriz\u00e1ci\u00f3 \u00e9s kationos polimeriz\u00e1ci\u00f3, gyakoribb a szabad gy\u00f6k\u00f6s polimeriz\u00e1ci\u00f3, ez a C-C polimeriz\u00e1ci\u00f3s t\u00e9rh\u00e1l\u00f3s\u00edt\u00f3 reakci\u00f3 merev t\u00e9rh\u00e1l\u00f3s\u00edt\u00e1s. A szabad gy\u00f6k\u00f6s polimeriz\u00e1ci\u00f3s reakci\u00f3 gyors, a zsugorod\u00e1s nagy; a polimeriz\u00e1ci\u00f3s fokv\u00e1ltoz\u00e1s kicsi, a blokkol\u00f3 polimeriz\u00e1ci\u00f3 hat\u00e1sa nagy (0,01-0,1% a blokkol\u00f3szer a reakci\u00f3 megakad\u00e1lyoz\u00e1s\u00e1ra). F\u00e9nykem\u00e9nyed\u0151 bevonatok gy\u00f3gy\u00edt\u00e1s ut\u00e1n t\u00e9rh\u00e1l\u00f3s\u00edt\u00f3 zsugorod\u00e1si ar\u00e1ny magas, a tanulm\u00e1ny meg\u00e1llap\u00edtotta, hogy a kett\u0151s k\u00f6t\u00e9s nem polimeriz\u00e1l\u00f3dik, ha a t\u00e1vols\u00e1ga hossz\u00fa, ha egyszer polimeriz\u00e1l\u00f3dik, a kovalens k\u00f6t\u00e9sek gener\u00e1l\u00e1sa, a t\u00e1vols\u00e1g r\u00f6vid\u00fclt, ami t\u00e9rfogatcs\u00f6kken\u00e9st okoz, minden tel\u00edtetlen polimeriz\u00e1ci\u00f3 kett\u0151s k\u00f6t\u00e9s zsugorod\u00e1sa ak\u00e1r 11%.<\/p>\n

A f\u00e9nyre kem\u00e9nyed\u0151 bevonatformul\u00e1k \u00f6sszetettek, a k\u00f6vetkez\u0151 teljes\u00edtm\u00e9nnyel.<\/p>\n

El\u0151sz\u00f6r is, sokf\u00e9le monomer \u00e9s sokf\u00e9le alapoligomer (gyanta) l\u00e9tezik. Jelenleg a szint\u00e9zis szerint a funkcion\u00e1lis csoportok, hogy osztani tel\u00edtetlen poli\u00e9szter oszt\u00e1ly PE, epoxi EA, poliuret\u00e1n oszt\u00e1ly PUA, poli\u00e9szter oszt\u00e1ly PEA, amino oszt\u00e1ly, poli\u00e9ter oszt\u00e1ly, poli\u00e9ter oszt\u00e1ly, szerves szil\u00edcium oszt\u00e1ly, foszf\u00e1t-\u00e9szter oszt\u00e1ly, vegyes oszt\u00e1ly, stb..<\/p>\n

M\u00e1sodszor, a funkci\u00f3ja szerint a f\u00e9nykem\u00e9nyed\u0151 bevonatok \u00e1ltal\u00e1nosan haszn\u00e1lt a gyanta a k\u00f6vetkez\u0151 kateg\u00f3ri\u00e1kba sorolhat\u00f3.<\/p>\n

1\u3001Kem\u00e9ny gyanta - Magas Tg, nagy kem\u00e9nys\u00e9g, j\u00f3 k\u00e9miai tulajdons\u00e1gok, a legt\u00f6bb kikem\u00e9nyed\u00e9si sebess\u00e9g. Mint p\u00e9ld\u00e1ul a standard biszfenol-A EA; magas funkci\u00f3s csoport\u00fa PUA \u00e9s kis molekulat\u00f6meg\u0171 2fPUA; magas funkci\u00f3s csoport\u00fa aminoakril\u00e1t; metakril\u00e1t oligomerek stb.<\/p>\n

2, l\u00e1gy gyanta - Tg kicsi, j\u00f3 rugalmass\u00e1g, lass\u00fa kem\u00e9nyed\u00e9si sebess\u00e9g, alacsony t\u00e9rh\u00e1l\u00f3s\u0171r\u0171s\u00e9g. Mint p\u00e9ld\u00e1ul m\u00f3dos\u00edtott epoxi - epoxi sz\u00f3jaolaj-akril\u00e1t, stb.; hossz\u00fa l\u00e1nc\u00fa poli\u00e9szter-akril\u00e1t; egyenes l\u00e1nc\u00fa szerkezet, amelynek \u00e1tlagos molekulat\u00f6mege t\u00f6bb mint 1200 PUA; n\u00e9h\u00e1ny tiszta akril\u00e1t oligomer, stb.<\/p>\n

3, pol\u00e1ris gyanta, az akt\u00edv hidrog\u00e9nt tartalmaz\u00f3 oligomer vagy k\u00f6nnyen hidrog\u00e9nk\u00f6t\u00e9seket k\u00e9pez, megv\u00e1ltoztathatja a polarit\u00e1st vagy a fel\u00fcleti fesz\u00fclts\u00e9get. Ilyen p\u00e9ld\u00e1ul a foszf\u00e1t-akril\u00e1t; szilikon oligomerek; karboxil-akril\u00e1t oligomerek stb.<\/p>\n

4, v\u00edzb\u00e1zis\u00fa UV oligomerek, k\u00f6z\u00f6s emulzi\u00f3s t\u00edpus, v\u00edzdiszperzi\u00f3s t\u00edpus, v\u00edzben old\u00f3d\u00f3 t\u00edpus.<\/p>\n

5, a nem t\u00e9rh\u00e1l\u00f3sod\u00f3 oszt\u00e1ly\u00fa gyant\u00e1k a f\u00e9nykem\u00e9nyed\u0151 bevonatok megfogalmaz\u00e1s\u00e1ban t\u00f6lt\u0151 szerepet t\u00f6ltenek be, jav\u00edtj\u00e1k a t\u00e9rh\u00e1l\u00f3s\u0171r\u0171s\u00e9get, n\u00f6velik a tapad\u00e1st, v\u00e1ltoztatj\u00e1k a rugalmass\u00e1got, jav\u00edtj\u00e1k a nedves\u00edthet\u0151s\u00e9get \u00e9s egy\u00e9b szerepeket. \u00c1ltal\u00e1ban ezek a gyant\u00e1k hossz\u00fa olajalkidgyanta; h\u0151re l\u00e1gyul\u00f3 akril\u00e1tgyanta; aldehid \u00e9s ketongyanta; k\u0151olajgyanta stb.<\/p>\n

Harmadszor, a tervez\u00e9s f\u00e9nykem\u00e9nyed\u0151 (UV) bevonat k\u00e9plete, amikor a v\u00e1laszt\u00e1s a gyanta.<\/p>\n

A bevonat k\u00e9plet\u00e9nek megtervez\u00e9se el\u0151tt a bevonat t\u00edpus\u00e1nak egy\u00e9rtelm\u0171nek kell lennie, azaz alapoz\u00f3, fed\u0151r\u00e9teg vagy sz\u00ednes fest\u00e9k; \u00e9s meg kell \u00e9rteni a bevont anyag alapvet\u0151 tulajdons\u00e1gait, mint p\u00e9ld\u00e1ul a polarit\u00e1s m\u00e9rete (fel\u00fcleti fesz\u00fclts\u00e9g), krist\u00e1lyosod\u00e1ssal vagy an\u00e9lk\u00fcl, a h\u0151re l\u00e1gyul\u00f3 vagy h\u0151re kem\u00e9nyed\u0151 anyaghoz tartoz\u00e1s stb. A konkr\u00e9t le\u00edr\u00e1s a k\u00f6vetkez\u0151.<\/p>\n

1, az alapoz\u00f3 gyanta kiv\u00e1laszt\u00e1sa. El\u0151sz\u00f6r is, ez a tapad\u00e1s k\u00f6vetelm\u00e9nye, amely az alapoz\u00f3 gyanta \u00e1ltal\u00e1noss\u00e1ga; nedves\u00edthet\u0151s\u00e9g, amely a sz\u00edn \u00e9s a t\u00f6lt\u0151anyag nedves\u00edt\u00e9s\u00e9re \u00e9s a szubsztr\u00e1t nedves\u00edt\u00e9s\u00e9re utal, amelyek k\u00e9t k\u00fcl\u00f6nb\u00f6z\u0151 k\u00f6vetelm\u00e9ny, mert a szubsztr\u00e1t \u00e9s a sz\u00ednes t\u00f6lt\u0151anyag fel\u00fcleti fesz\u00fclts\u00e9ge nem lesz pontosan ugyanaz; rugalmass\u00e1g, amely els\u0151sorban a csiszol\u00e1st \u00e9s a r\u00e9tegek k\u00f6z\u00f6tti tapad\u00e1st foglalja mag\u00e1ban.<\/p>\n

2\u3001A gyanta kiv\u00e1laszt\u00e1sa a fed\u0151r\u00e9teghez. A fed\u0151r\u00e9teg teljes\u00edtm\u00e9ny\u00e9t \u00e9s a gyanta kiv\u00e1laszt\u00e1s\u00e1t az al\u00e1bbiakban ismertetj\u00fck.<\/p>\n

A film teljess\u00e9ge \u00e9s egyenletess\u00e9ge. Ennek a k\u00f6vetelm\u00e9nynek az el\u00e9r\u00e9s\u00e9hez j\u00f3 kompatibilit\u00e1s\u00fa gyant\u00e1kat \u00e9s monomereket kell v\u00e1lasztani, jav\u00edtani kell a nedves\u00edt\u00e9st \u00e9s a kiegyenl\u00edt\u00e9st az alapoz\u00f3val, megfelel\u0151en n\u00f6velni kell a t\u00e9rh\u00e1l\u00f3sod\u00e1si fokot, \u00e9s magasabb t\u00f6r\u00e9smutat\u00f3j\u00fa gyant\u00e1t kell v\u00e1lasztani.<\/p>\n

Sz\u00edv\u00f3ss\u00e1g, els\u0151sorban a kem\u00e9nys\u00e9get \u00e9s a kop\u00e1s\u00e1ll\u00f3s\u00e1got foglalja mag\u00e1ban. Ez a k\u00e9t tulajdons\u00e1g \u00f6sszef\u00fcgg, de nem felt\u00e9tlen\u00fcl azonos, \u00e9s k\u00fcl\u00f6nb\u00f6z\u0151k\u00e9ppen kell kezelni.<\/p>\n

R\u00e9tegk\u00f6zi tapad\u00e1s. A r\u00e9tegk\u00f6zi tapad\u00e1s megold\u00e1s\u00e1nak meg kell felelnie a nedves\u00edt\u00e9snek \u00e9s a kiegyenl\u00edt\u00e9snek, valamint a gyanta polarit\u00e1s\u00e1nak.<\/p>\n

EA, PUA (poli\u00e9szter) j\u00f3 k\u00e9miai ellen\u00e1ll\u00e1s, PE, poli\u00e9ter rosszabb; \u00e1ltal\u00e1ban, alif\u00e1s PUA, tiszta poli\u00e9ter-akril\u00e1t, tiszta C, amino oszt\u00e1ly j\u00f3 s\u00e1rgul\u00e1s ellen\u00e1ll\u00e1s, a megfelel\u0151 s\u00e1rgul\u00e1sg\u00e1tl\u00f3 szer hozz\u00e1ad\u00e1s\u00e1nak formul\u00e1z\u00e1sa is hat\u00e9konyan fokozza a fed\u0151r\u00e9teg s\u00e1rgul\u00e1s ellen\u00e1ll\u00e1s\u00e1t.<\/p>\n

Matt k\u00f6vetelm\u00e9ny. N\u00e9h\u00e1ny kiss\u00e9 kisebb molekulat\u00f6meg\u0171 vagy nagyon nagy molekulat\u00f6meg\u0171 gyanta bizonyos matt hat\u00e1st kelt; n\u00e9h\u00e1ny poliuret\u00e1ngyanta matt hat\u00e1sa is j\u00f3.<\/p>","protected":false},"excerpt":{"rendered":"

UV oligomerek haszn\u00e1lt f\u00e9nyre kem\u00e9nyed\u0151 bevonatok f\u00e9nyre kem\u00e9nyed\u0151 bevonatok haszn\u00e1lt oligomer is ismert, mint prepolimer, amely egy kis molekulat\u00f6meg\u0171, jellemz\u0151i a polimeriz\u00e1ci\u00f3s csoportok, viszkozit\u00e1s, a f\u0151 test f\u00e9nyre kem\u00e9nyed\u0151 bevonatok film. A f\u00e9nykem\u00e9nyed\u00e9s a tel\u00edtetlen molekul\u00e1k k\u00f6z\u00f6tti polimeriz\u00e1ci\u00f3s reakci\u00f3, az inici\u00e1tor ind\u00edt\u00f3 mechanizmusa szerint szabad gy\u00f6k\u00f6k vannak [...]<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[114],"tags":[],"class_list":["post-5596","post","type-post","status-publish","format-standard","hentry","category-catalysts-chemical-auxiliary-agents"],"yoast_head":"\nUV oligomers used in light-curing coatings - Longchang Chemical<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/longchangchemical.com\/hu\/uv-oligomers-used-in-light-curing-coatings\/\" \/>\n<meta property=\"og:locale\" content=\"hu_HU\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"UV oligomers used in light-curing coatings - Longchang Chemical\" \/>\n<meta property=\"og:description\" content=\"UV oligomers used in light-curing coatings Light-curing coatings used oligomer is also known as prepolymer, which has a small molecular weight, has the characteristics of polymerization groups, viscosity, is the main body of light-curing coatings film. Light curing is the polymerization reaction between unsaturated molecules, according to the initiator initiation mechanism, there are free radical […]\" \/>\n<meta property=\"og:url\" content=\"https:\/\/longchangchemical.com\/hu\/uv-oligomers-used-in-light-curing-coatings\/\" \/>\n<meta property=\"og:site_name\" content=\"Longchang Chemical\" \/>\n<meta property=\"article:published_time\" content=\"2022-09-23T08:37:38+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/longchangchemical.com\/wp-content\/uploads\/2024\/02\/logo-jpeg.jpg\" \/>\n\t<meta property=\"og:image:width\" content=\"1000\" \/>\n\t<meta property=\"og:image:height\" content=\"1000\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/jpeg\" \/>\n<meta name=\"author\" content=\"Longchang Chemical\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/#article\",\"isPartOf\":{\"@id\":\"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/\"},\"author\":{\"name\":\"Longchang Chemical\",\"@id\":\"https:\/\/longchangchemical.com\/#\/schema\/person\/ecb1ad846136c6f1ca534b62978c6a8e\"},\"headline\":\"UV oligomers used in light-curing coatings\",\"datePublished\":\"2022-09-23T08:37:38+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/\"},\"wordCount\":687,\"publisher\":{\"@id\":\"https:\/\/longchangchemical.com\/#organization\"},\"articleSection\":[\"Catalysts & Chemical Auxiliary Agents\"],\"inLanguage\":\"hu\"},{\"@type\":\"WebPage\",\"@id\":\"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/\",\"url\":\"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/\",\"name\":\"UV oligomers used in light-curing coatings - 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Light curing is the polymerization reaction between unsaturated molecules, according to the initiator initiation mechanism, there are free radical […]","og_url":"https:\/\/longchangchemical.com\/hu\/uv-oligomers-used-in-light-curing-coatings\/","og_site_name":"Longchang Chemical","article_published_time":"2022-09-23T08:37:38+00:00","og_image":[{"width":1000,"height":1000,"url":"https:\/\/longchangchemical.com\/wp-content\/uploads\/2024\/02\/logo-jpeg.jpg","type":"image\/jpeg"}],"author":"Longchang Chemical","twitter_card":"summary_large_image","schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"Article","@id":"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/#article","isPartOf":{"@id":"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/"},"author":{"name":"Longchang Chemical","@id":"https:\/\/longchangchemical.com\/#\/schema\/person\/ecb1ad846136c6f1ca534b62978c6a8e"},"headline":"UV oligomers used in light-curing coatings","datePublished":"2022-09-23T08:37:38+00:00","mainEntityOfPage":{"@id":"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/"},"wordCount":687,"publisher":{"@id":"https:\/\/longchangchemical.com\/#organization"},"articleSection":["Catalysts & Chemical Auxiliary Agents"],"inLanguage":"hu"},{"@type":"WebPage","@id":"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/","url":"https:\/\/longchangchemical.com\/uv-oligomers-used-in-light-curing-coatings\/","name":"UV oligomerek f\u00e9nyre kem\u00e9nyed\u0151 bevonatokban - 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