{"id":5412,"date":"2022-07-27T13:50:42","date_gmt":"2022-07-27T13:50:42","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=5412"},"modified":"2022-07-27T13:51:28","modified_gmt":"2022-07-27T13:51:28","slug":"pet-nucleating-agents","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/hu\/pet-nucleating-agents\/","title":{"rendered":"A PET magk\u00e9pz\u0151 anyagok t\u00edpusainak r\u00f6vid le\u00edr\u00e1sa \u00e9s a magk\u00e9pz\u0151 anyagok hat\u00e1sa a PET krist\u00e1lyos tulajdons\u00e1gaira"},"content":{"rendered":"<h1><strong>A PET magk\u00e9pz\u0151 anyagok t\u00edpusainak r\u00f6vid le\u00edr\u00e1sa \u00e9s a magk\u00e9pz\u0151 anyagok hat\u00e1sa a PET krist\u00e1lyos tulajdons\u00e1gaira<\/strong><\/h1>\n<p>&nbsp;<\/p>\n<p>A PET eset\u00e9ben a nukle\u00e1l\u00f3szerek h\u00e1rom f\u0151 t\u00edpusa l\u00e9tezik, nevezetesen a szervetlen nukle\u00e1l\u00f3szerek, a szerves nukle\u00e1l\u00f3szerek \u00e9s a polimer nukle\u00e1l\u00f3szerek. Ez a cikk r\u00f6viden ismerteti ezeknek a nukle\u00e1l\u00f3szereknek a PET krist\u00e1lyos tulajdons\u00e1gaira gyakorolt hat\u00e1s\u00e1t.<\/p>\n<p>I. Szervetlen nukle\u00e1l\u00f3 anyagok.<\/p>\n<p>Szervetlen nukle\u00e1l\u00f3 szerek alapvet\u0151en szervetlen t\u00f6lt\u0151anyagok \u00e1ltal\u00e1nosan haszn\u00e1lt polimerek, szervetlen nukle\u00e1l\u00f3 szerek a krist\u00e1lyos\u00edt\u00e1si folyamat egyen\u00e9rt\u00e9k\u0171 a m\u00e1sodik f\u00e1zisban a kis r\u00e9szecsk\u00e9k a PET olvad\u00e9k, magas h\u0151m\u00e9rs\u00e9kleten ezek a r\u00e9szecsk\u00e9k nem olvadt \u00e1llapotban, a folyamat a h\u0171t\u00e9s, PET molekul\u00e1ris l\u00e1nc, hogy ezek a r\u00e9szecsk\u00e9k, mint a k\u00f6zpont, adszorbe\u00e1l\u00f3dott a r\u00e9szecsk\u00e9k \u00e9s a rendezett elrendez\u00e9s \u00e9s a magok kialakul\u00e1s\u00e1t. Ezek a kis szervetlen molekul\u00e1k, ha heterog\u00e9n magk\u00e9pz\u0151 anyagk\u00e9nt haszn\u00e1lj\u00e1k \u0151ket, ez\u00e9rt cs\u00f6kkentik a PET-ben a magok kialakul\u00e1s\u00e1hoz sz\u00fcks\u00e9ges aktiv\u00e1l\u00e1si energi\u00e1t, \u00e9s kev\u00e9s hat\u00e1ssal vannak a k\u00e9s\u0151bbi krist\u00e1lyosod\u00e1si folyamatra, azaz a PET molekulal\u00e1nc szegmensek a magok fel\u00fclet\u00e9re adszorbe\u00e1l\u00f3dnak \u00e9s bel\u00e9pnek a r\u00e1csba.<\/p>\n<p>Amikor a talkumot nukle\u00e1l\u00f3 anyagk\u00e9nt haszn\u00e1lj\u00e1k a PET-ben, a kezdeti krist\u00e1lyosod\u00e1s a t\u00f6lt\u0151anyag-r\u00e9szecsk\u00e9k fel\u00fclet\u00e9n alakul ki, \u00e9s a krist\u00e1lyoknak a lamell\u00e1ris szerkezetb\u0151l a r\u00e9szecsk\u00e9k fel\u00fclet\u00e9n t\u00f6rt\u00e9n\u0151 kis later\u00e1lis diff\u00fazi\u00f3val t\u00f6rt\u00e9n\u0151 \u00e1tvitele k\u00eds\u00e9ri. A karbon\u00e1toknak mint nukle\u00e1l\u00f3szereknek a PET krist\u00e1lyos tulajdons\u00e1gaira gyakorolt hat\u00e1s\u00e1t Na2CO3, \u00e9s NaHCO3 krist\u00e1lyos nukle\u00e1l\u00f3szerk\u00e9nt a PET eset\u00e9ben hat\u00e9konynak tal\u00e1lt\u00e1k. Na2CO3 vagy NaHCO3 mint nukle\u00e1l\u00f3 szerekkel a PET j\u00f3 mechanikai tulajdons\u00e1gokkal \u00e1ll\u00edthat\u00f3 el\u0151 viszonylag r\u00f6vid form\u00e1z\u00e1si ciklusban, 90% formah\u0151m\u00e9rs\u00e9kleten. \u00d6sszehasonl\u00edtott\u00e1k a talkum, a CaCO3 \u00e9s a szerves n\u00e1triums\u00f3 nukle\u00e1l\u00f3szerek nukle\u00e1ci\u00f3s hat\u00e1s\u00e1t, \u00e9s meg\u00e1llap\u00edtott\u00e1k, hogy a talkum kedvez\u0151bb a PET krist\u00e1lyosod\u00e1si sebess\u00e9g\u00e9re, mint a CaCO3. Ha a talkum t\u00f6megtartalma 5%, a PET izotermikus krist\u00e1lyosod\u00e1si sebess\u00e9g\u00e9hez val\u00f3 hozz\u00e1j\u00e1rul\u00e1sa k\u00f6zel azonos a 1% szerves n\u00e1triums\u00f3 hozz\u00e1j\u00e1rul\u00e1s\u00e1val, \u00e9s a talkum hozz\u00e1ad\u00e1sa jelent\u0151sen jav\u00edtja a PET szak\u00edt\u00f3szil\u00e1rds\u00e1g\u00e1t \u00e9s hajl\u00edt\u00f3szil\u00e1rds\u00e1g\u00e1t, m\u00edg a szerves n\u00e1triums\u00f3 cs\u00f6kkenti ezeket a tulajdons\u00e1gokat.<\/p>\n<p>M\u00e1sodszor, szerves nukle\u00e1l\u00f3 anyagok.<\/p>\n<p>A szerves nukle\u00e1l\u00f3szerek els\u0151sorban a monokarbonsav Na, Li, Ba, Mg, Ca s\u00f3i, a benzoesav Na, K, Ca s\u00f3i, az arom\u00e1s hidroxiszulfon\u00e1tok, a szerves foszforvegy\u00fcletek Mg, Zn s\u00f3i, amelyek k\u00f6z\u00fcl a jobb hat\u00e1s\u00fa a karbonsav n\u00e1triums\u00f3ja \u00e9s a karbonsav k\u00e1liums\u00f3ja. A szerves nukle\u00e1l\u00f3szerek nukle\u00e1ci\u00f3s mechanizmusa els\u0151sorban k\u00e9miai szerkezet\u00fckkel f\u00fcgg \u00f6ssze. A PET \u00e9s a n\u00e1trium-karboxil\u00e1t s\u00f3k magas h\u0151m\u00e9rs\u00e9kleten t\u00f6rt\u00e9n\u0151 extrud\u00e1l\u00e1skor k\u00e9miai reakci\u00f3ba l\u00e9pnek, \u00e9s PET-COONa anyagokat hoznak l\u00e9tre, amelyek ionos v\u00e9gcsoportokkal ionos klasztereket k\u00e9peznek a PET-olvad\u00e9k k\u00f6z\u00f6tt.<\/p>\n<p>A n\u00e1trium-benzo\u00e1t-sz\u00e1rmaz\u00e9k (Nu) nukle\u00e1l\u00f3szer \u00e9s poli\u00e9szter-poli\u00e9ter kopolimer krist\u00e1lyosod\u00e1st el\u0151seg\u00edt\u0151 anyag (Pro) hozz\u00e1ad\u00e1s\u00e1nak hat\u00e1sa a PET krist\u00e1lyosod\u00e1si sebess\u00e9g\u00e9re. A Nu\/Pro-PET 228 \u00b0C \u00e9s 230 \u00b0C krist\u00e1lyos\u00edt\u00e1si h\u0151m\u00e9rs\u00e9kleten kiss\u00e9 gyorsabban krist\u00e1lyosodott, mint a Nu-PET; magasabb krist\u00e1lyos\u00edt\u00e1si h\u0151m\u00e9rs\u00e9kleten azonban a Nu\/Pro-PET kiss\u00e9 lassabban krist\u00e1lyosodott, mint a Nu-PET, ami azt jelzi, hogy a krist\u00e1lyos\u00edt\u00e1s Ez a gyors\u00edt\u00f3 nem n\u00f6velte tov\u00e1bb a PET krist\u00e1lyos\u00edt\u00e1si sebess\u00e9g\u00e9t magasabb h\u0151m\u00e9rs\u00e9kleten. A n\u00e1trium-benzo\u00e1t nukle\u00e1l\u00f3szer hozz\u00e1ad\u00e1sa r\u00f6videbb krist\u00e1lyosod\u00e1si indukci\u00f3s id\u0151t, cs\u00f6kkent krist\u00e1lyosod\u00e1si aktiv\u00e1l\u00e1si energi\u00e1t \u00e9s a PET teljes krist\u00e1lyosod\u00e1si sebess\u00e9g\u00e9nek n\u00f6veked\u00e9s\u00e9t eredm\u00e9nyezte; \u00e9s a vari\u00e1ci\u00f3 a hozz\u00e1ad\u00e1s n\u00f6vel\u00e9s\u00e9vel n\u0151tt, de cs\u00f6kkentette a krist\u00e1lyoss\u00e1got, ami nem volt kedvez\u0151 a kevert anyag tulajdons\u00e1gainak stabilit\u00e1sa szempontj\u00e1b\u00f3l. Ez\u00e9rt a n\u00e1trium-benzo\u00e1t PET-ben val\u00f3 alkalmaz\u00e1sakor figyelmet kell ford\u00edtani az adagol\u00e1sra, \u00e9s m\u00e1s m\u00f3dos\u00edt\u00f3kkal egy\u00fctt is sz\u00fcks\u00e9ges haszn\u00e1lni.<\/p>\n<p>Harmadszor, polimer nukle\u00e1l\u00f3 anyagok.<\/p>\n<p>A polimer magk\u00e9pz\u0151 anyagok k\u00f6z\u00e9 tartoznak a poli\u00e9szter zwitterionos alk\u00e1lif\u00e9ms\u00f3i, az \u00f6sszes arom\u00e1s poli\u00e9szterpor, a PTFE por, az alacsony molekulat\u00f6meg\u0171 izotaktikus PP, a magas olvad\u00e1spont\u00fa PET, az ionomer, a folyad\u00e9kkrist\u00e1lyos polimer (LCP) stb., amelyek k\u00f6z\u00fcl az ionomer egy \u00e1ltal\u00e1nosan haszn\u00e1lt PET krist\u00e1lyos polimer anyag. A PET \u00fcvegesed\u00e9si \u00e1tmeneti h\u0151m\u00e9rs\u00e9klete kever\u00e9ssel cs\u00f6kken, ami felgyors\u00edtja a krist\u00e1lyosod\u00e1si sebess\u00e9get \u00e9s jav\u00edtja az \u00fct\u00e9s\u00e1ll\u00f3s\u00e1got. Az ionomerek olyan polimerekre utalnak, amelyek polimer gerinc\u00e9n kis sz\u00e1m\u00fa ioniz\u00e1lhat\u00f3 csoport tal\u00e1lhat\u00f3, a f\u0151 komponensek egy nem ionos gerincl\u00e1ncb\u00f3l \u00e9s kis sz\u00e1m\u00fa iontartalm\u00fa komponensb\u0151l \u00e1llnak. Az ionos csoportok mol\u00e1ris tartalma \u00e1ltal\u00e1ban legfeljebb 15%. Az ionomerek bin\u00e1ris kever\u00e9si rendszer\u00e9ben az ionomer k\u00f6lcs\u00f6nhat\u00e1sba l\u00e9phet ion a ion, ion a dip\u00f3lus, hidrog\u00e9nk\u00f6t\u00e9s, savak \u00e9s b\u00e1zisok, t\u00f6lt\u00e9s\u00e1tvitel, \u00e1tmeneti f\u00e9m koordin\u00e1ci\u00f3s komplexek stb. r\u00e9v\u00e9n, valamint a polimerl\u00e1ncok k\u00f6z\u00f6tt kialakul\u00f3 t\u00f6bbsz\u00f6r\u00f6s ionp\u00e1rok vagy ionklaszterek fizikai keresztk\u00f6t\u00e9se r\u00e9v\u00e9n. Az ionomerek e k\u00fcl\u00f6nleges \u00f6sszet\u00e9tele \u00e9s morfol\u00f3giai szerkezete sz\u00e1mos egyedi tulajdons\u00e1got k\u00f6lcs\u00f6n\u00f6z nekik, p\u00e9ld\u00e1ul kiv\u00e1l\u00f3 sz\u00edv\u00f3ss\u00e1got, nagy \u00fct\u00e9s\u00e1ll\u00f3s\u00e1got, kop\u00e1s\u00e1ll\u00f3s\u00e1got, \u00e1tl\u00e1that\u00f3s\u00e1got \u00e9s magas olvad\u00e9kviszkozit\u00e1st. A Surlyn egy sz\u00e9les k\u00f6rben haszn\u00e1lt ionomer, amelyet a DuPont fejlesztett ki Surlyn nukle\u00e1l\u00f3szerk\u00e9nt, amely az etil\u00e9n-metakrilsav kopolimer n\u00e1triums\u00f3ja, ahol az etil\u00e9n\/methakrilsav s\u00falyar\u00e1nya 90\/10, a n\u00e1trium semleges\u00edt\u00e9se pedig kb. 45%. A reakci\u00f3term\u00e9kek iontermin\u00e1lt ionos klasztereket (PET-COONa) k\u00e9pezhetnek, amelyek heterog\u00e9n nukle\u00e1l\u00f3 anyagk\u00e9nt m\u0171k\u00f6dnek a h\u0171t\u00e9ses krist\u00e1lyos\u00edt\u00e1si folyamatban.<\/p>\n<p>\u00d6sszehasonl\u00edtva a kis molekul\u00e1j\u00fa szerves nukle\u00e1l\u00f3 szerek, polimer nukle\u00e1l\u00f3 szer Surlyn ion v\u00e9gcsoportok a gener\u00e1ci\u00f3s nagy molekul\u00e1k ugyanakkor van PET-R (R szerves nukle\u00e1l\u00f3 szer rugalmas csoport) gener\u00e1lt, mert R molekulal\u00e1nc, mint PET molekulal\u00e1nc rugalmasabb, a rendszerben, \u00e9s szerepet j\u00e1tszanak a k\u00f6nny\u00edt\u0151, a bevezet\u00e9se, hogy el\u0151seg\u00edtse a molekul\u00e1ris mozg\u00e1s a PET, cs\u00f6kkenti a szabad energia a molekulal\u00e1nc diff\u00fazi\u00f3 a karakter, \u00e9s cs\u00f6kkenti a PET csempe, jav\u00edtja a PET. Cs\u00f6kkenti a PET csemp\u00e9t is, \u00e9s n\u00f6veli a PET krist\u00e1lyosod\u00e1si sebess\u00e9g\u00e9t, ami a kis molekulat\u00f6meg\u0171 nukle\u00e1l\u00f3 szerek eset\u00e9ben nem \u00e1ll fenn.<\/p>","protected":false},"excerpt":{"rendered":"<p>A PET nukle\u00e1l\u00f3szerek t\u00edpusainak r\u00f6vid le\u00edr\u00e1sa \u00e9s a nukle\u00e1l\u00f3szerek hat\u00e1sa a PET krist\u00e1lyos tulajdons\u00e1gaira A PET nukle\u00e1l\u00f3szerek h\u00e1rom f\u0151 t\u00edpusa l\u00e9tezik, nevezetesen a szervetlen nukle\u00e1l\u00f3szerek, a szerves nukle\u00e1l\u00f3szerek \u00e9s a polimer nukle\u00e1l\u00f3szerek. Ez az \u00edr\u00e1s r\u00f6viden ismerteti ezeknek a nukle\u00e1l\u00f3szereknek a hat\u00e1s\u00e1t a [...].<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[106],"tags":[],"class_list":["post-5412","post","type-post","status-publish","format-standard","hentry","category-laboratory-news"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.3.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Brief description of the types of PET nucleating agents and the effect of nucleating agents on the crystalline properties of PET - Longchang Chemical<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/longchangchemical.com\/hu\/pet-nucleating-agents\/\" \/>\n<meta property=\"og:locale\" content=\"hu_HU\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Brief description of the types of PET nucleating agents and the effect of nucleating agents on the crystalline properties of PET - Longchang Chemical\" \/>\n<meta property=\"og:description\" content=\"Brief description of the types of PET nucleating agents and the effect of nucleating agents on the crystalline properties of PET &nbsp; There are three main types of nucleating agents for PET, namely inorganic nucleating agents, organic nucleating agents and polymeric nucleating agents. 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