{"id":5401,"date":"2022-07-23T13:33:09","date_gmt":"2022-07-23T13:33:09","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=5401"},"modified":"2022-07-23T13:33:09","modified_gmt":"2022-07-23T13:33:09","slug":"what-are-the-elements-in-selecting-uv-oligomers-for-light-curing-coating-formulations","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/hu\/what-are-the-elements-in-selecting-uv-oligomers-for-light-curing-coating-formulations\/","title":{"rendered":"Melyek az UV oligomerek kiv\u00e1laszt\u00e1s\u00e1nak elemei a f\u00e9nyre kem\u00e9nyed\u0151 bevonatformul\u00e1khoz?"},"content":{"rendered":"

Melyek az UV oligomerek kiv\u00e1laszt\u00e1s\u00e1nak elemei a f\u00e9nyre kem\u00e9nyed\u0151 bevonatformul\u00e1khoz?<\/strong><\/h1>\n

A f\u00e9nyre kem\u00e9nyed\u0151 bevonatokat UV-kem\u00e9nyed\u0151 bevonatoknak is nevezik, amelyek UV-f\u00e9nyt haszn\u00e1lnak energiaforr\u00e1sk\u00e9nt a bevonat kem\u00e9ny\u00edt\u00e9s\u00e9hez. Gyorsan, h\u0151 ig\u00e9nybev\u00e9tele n\u00e9lk\u00fcl kem\u00e9ny\u00edthet\u0151k olyan hordoz\u00f3kon, mint a pap\u00edr, a m\u0171anyag, a b\u0151r \u00e9s a fa. A f\u00e9nyre kem\u00e9nyed\u0151 bevonatok f\u0151k\u00e9nt f\u00e9nyre kem\u00e9nyed\u0151 gyant\u00e1kb\u00f3l (oligomerekb\u0151l), fotoinici\u00e1torokb\u00f3l (f\u00e9ny\u00e9rz\u00e9keny\u00edt\u0151kb\u0151l), h\u00edg\u00edt\u00f3kb\u00f3l \u00e9s adal\u00e9kanyagokb\u00f3l \u00e1llnak. A f\u00e9nyre kem\u00e9nyed\u0151 gyant\u00e1k \u00e1ltal\u00e1ban alacsony molekulat\u00f6meg\u0171, tel\u00edtetlen k\u00f6t\u00e9sekkel rendelkez\u0151 gyant\u00e1k, mint p\u00e9ld\u00e1ul tel\u00edtetlen poli\u00e9szterek, akril oligomerek stb. Ez a cikk a f\u00e9nyre kem\u00e9nyed\u0151 gyanta (oligomer) kiv\u00e1laszt\u00e1s\u00e1nak elemeit t\u00e1rgyalja a f\u00e9nyre kem\u00e9nyed\u0151 fest\u00e9kk\u00e9sz\u00edtm\u00e9nyekben.<\/p>\n

I. Viszkozit\u00e1s.<\/p>\n

Az alacsony viszkozit\u00e1s\u00fa gyanta kiv\u00e1laszt\u00e1sa cs\u00f6kkentheti az akt\u00edv h\u00edg\u00edt\u00f3szer mennyis\u00e9g\u00e9t. De az alacsony viszkozit\u00e1s\u00fa gyanta gyakran alacsony relat\u00edv molekulat\u00f6meg\u0171, ami befoly\u00e1solja a kikem\u00e9ny\u00edtett film fizikai \u00e9s mechanikai tulajdons\u00e1gait.<\/p>\n

M\u00e1sodszor, a f\u00e9nykem\u00e9nyed\u00e9s m\u00e9rt\u00e9ke.<\/p>\n

\u00c1ltal\u00e1noss\u00e1gban elmondhat\u00f3, hogy min\u00e9l magasabb a f\u00e9nykem\u00e9nyed\u0151 gyanta funkcion\u00e1lis foka, ann\u00e1l gyorsabb a f\u00e9nykem\u00e9nyed\u00e9si sebess\u00e9g, az epoxiakril\u00e1t f\u00e9nykem\u00e9nyed\u00e9si sebess\u00e9ge gyors, az amin m\u00f3dos\u00edtott oligomer f\u00e9nykem\u00e9nyed\u00e9si sebess\u00e9ge szint\u00e9n gyors. Nagyon fontos felt\u00e9tel a gyors f\u00e9nykem\u00e9nyed\u00e9si sebess\u00e9g\u0171 gyanta kiv\u00e1laszt\u00e1sa, amely nemcsak a fotoinici\u00e1tor mennyis\u00e9g\u00e9t cs\u00f6kkentheti, hanem megfelel a f\u00e9nykem\u00e9nyed\u0151 bevonatsor gyors kem\u00e9nyed\u00e9s\u00e9nek k\u00f6vetelm\u00e9nyeinek is.<\/p>\n

Harmadszor, fizikai \u00e9s mechanikai tulajdons\u00e1gok.<\/p>\n

A f\u00e9nykem\u00e9nyed\u0151 fest\u00e9kfilm fizikai \u00e9s mechanikai tulajdons\u00e1gait els\u0151sorban a f\u00e9nykem\u00e9nyed\u0151 gyanta kem\u00e9nyed\u0151 film teljes\u00edtm\u00e9nye hat\u00e1rozza meg, \u00e9s a f\u00e9nykem\u00e9nyed\u0151 fest\u00e9k k\u00fcl\u00f6nb\u00f6z\u0151 fajt\u00e1inak fizikai \u00e9s mechanikai tulajdons\u00e1gai elt\u00e9r\u0151ek, a f\u00e9nykem\u00e9nyed\u0151 gyanta kiv\u00e1laszt\u00e1sa is elt\u00e9r\u0151. A fest\u00e9kfilm fizikai \u00e9s mechanikai tulajdons\u00e1gai els\u0151sorban a k\u00f6vetkez\u0151 mutat\u00f3k.<\/p>\n

Kem\u00e9nys\u00e9g, epoxi akril\u00e1t \u00e9s tel\u00edtetlen poli\u00e9szter \u00e1ltal\u00e1nos kem\u00e9nys\u00e9g, benzol gy\u0171r\u0171s szerkezet\u0171 oligomer is el\u0151seg\u00edti a kem\u00e9nys\u00e9g jav\u00edt\u00e1s\u00e1t. Nagy funkcionalit\u00e1s, nagy t\u00e9rh\u00e1l\u00f3s\u0171r\u0171s\u00e9g, magas Tg \u00e9s nagy kem\u00e9nys\u00e9g.<\/p>\n

Rugalmass\u00e1g, az uret\u00e1n-akrilok, a poli\u00e9szter-akrilok, a poli\u00e9ter-akrilok \u00e9s a tiszta akrilok \u00e1ltal\u00e1ban rugalmasabbak. Az oligomerek alif\u00e1s, hossz\u00fa sz\u00e9nl\u00e1nc\u00fa szerkezet\u0171 alif\u00e1s l\u00e1ncokat tartalmaznak \u00e9s rugalmasak. Min\u00e9l nagyobb a relat\u00edv molekulat\u00f6meg, ann\u00e1l jobb a rugalmass\u00e1g. Alacsony t\u00e9rh\u00e1l\u00f3s\u0171r\u0171s\u00e9g, j\u00f3 rugalmass\u00e1g. alacsony Tg, j\u00f3 hajl\u00edt\u00f3 v\u00e1g\u00e1s.<\/p>\n

Kop\u00e1s\u00e1ll\u00f3s\u00e1g, az uret\u00e1n-akrilgyanta j\u00f3 kop\u00e1s\u00e1ll\u00f3s\u00e1ggal rendelkezik. Az oligomerek j\u00f3 kop\u00e1s\u00e1ll\u00f3s\u00e1ga a molekul\u00e1k k\u00f6z\u00f6tti hidrog\u00e9nk\u00f6t\u00e9sek k\u00f6nny\u0171 kialakul\u00e1s\u00e1val. Nagy keresztk\u00f6t\u00e9s-s\u0171r\u0171s\u00e9g, j\u00f3 kop\u00e1s\u00e1ll\u00f3s\u00e1g.<\/p>\n

Szak\u00edt\u00f3szil\u00e1rds\u00e1g, az epoxiakril\u00e1tok \u00e9s a tel\u00edtetlen poli\u00e9szterek nagy szak\u00edt\u00f3szil\u00e1rds\u00e1ggal, \u00e1ltal\u00e1ban nagyobb relat\u00edv molekulat\u00f6meggel, nagyobb polarit\u00e1ssal, kisebb rugalmass\u00e1ggal \u00e9s magasabb t\u00e9rh\u00e1l\u00f3sodott oligomerek nagyobb szak\u00edt\u00f3szil\u00e1rds\u00e1ggal rendelkeznek.<\/p>\n

\u00dct\u00e9s\u00e1ll\u00f3s\u00e1g, az uret\u00e1n akrilgyant\u00e1k, a poli\u00e9szter akrilgyant\u00e1k, a poli\u00e9ter akrilgyant\u00e1k \u00e9s a tiszta akrilok jobb \u00fct\u00e9s\u00e1ll\u00f3s\u00e1ggal rendelkeznek. Alacsony Tg, rugalmas oligomerek \u00e1ltal\u00e1ban j\u00f3 \u00fct\u00e9s\u00e1ll\u00f3s\u00e1ggal.<\/p>\n

Tapad\u00e1s, alacsony zsugorod\u00e1s\u00fa oligomerek, j\u00f3 tapad\u00e1s a szubsztr\u00e1tokhoz; az olyan csoportokat tartalmaz\u00f3 oligomerek, mint a -OH \u00e9s -COOH, j\u00f3l tapadnak a f\u00e9mekhez. Alacsony fel\u00fcleti fesz\u00fclts\u00e9g\u0171 oligomerek, j\u00f3 nedvesed\u00e9s \u00e9s terjed\u00e9s a szubsztr\u00e1tokon, j\u00f3 tapad\u00e1s.<\/p>\n

S\u00e1rgul\u00e1s\u00e1ll\u00f3s\u00e1g, az alif\u00e1s poliuret\u00e1n akrilgyant\u00e1k, a poli\u00e9ter akrilgyant\u00e1k \u00e9s a tiszta akrilok j\u00f3l ellen\u00e1llnak a s\u00e1rgul\u00e1snak. A megfelel\u0151 s\u00e1rgul\u00e1sg\u00e1tl\u00f3 szerek hozz\u00e1ad\u00e1sa a formul\u00e1hoz gyakran hat\u00e9konyan jav\u00edtja a f\u00e9nyre kem\u00e9nyed\u0151 bevonatok s\u00e1rgul\u00e1ssal szembeni ellen\u00e1ll\u00e1s\u00e1t.<\/p>\n

K\u00e9miai ellen\u00e1ll\u00e1s, az epoxiakril\u00e1tok, a poliuret\u00e1n-akril\u00e1tok \u00e9s a poli\u00e9szter-akril\u00e1tok mind j\u00f3 k\u00e9miai ellen\u00e1ll\u00e1ssal rendelkeznek, de a poli\u00e9szter-akril\u00e1tok kev\u00e9sb\u00e9 ellen\u00e1ll\u00f3ak a l\u00fagokkal szemben; a t\u00e9rh\u00e1l\u00f3sod\u00e1si s\u0171r\u0171s\u00e9g n\u00f6vel\u00e9se a kem\u00e9nyed\u00e9s sor\u00e1n n\u00f6veli a term\u00e9k k\u00e9miai ellen\u00e1ll\u00e1s\u00e1t.<\/p>\n

F\u00e9nyess\u00e9g, epoxi akril\u00e1tok \u00e9s tel\u00edtetlen poli\u00e9szterek magas f\u00e9nyess\u00e9g, a t\u00e9rh\u00e1l\u00f3s\u0171r\u0171s\u00e9g n\u0151, a f\u00e9nyess\u00e9g n\u0151. magas Tg, magas t\u00f6r\u00e9smutat\u00f3 az oligomerek j\u00f3 f\u00e9nyess\u00e9g.<\/p>\n

A pigmentek nedves\u00edthet\u0151s\u00e9ge, \u00e1ltal\u00e1ban a zs\u00edrsavval m\u00f3dos\u00edtott \u00e9s az aminnal m\u00f3dos\u00edtott oligomerek jobban nedves\u00edtik a pigmenteket, a -OH \u00e9s -COOH oligomereket tartalmaz\u00f3 oligomerek szint\u00e9n jobban nedves\u00edtik a pigmenteket.<\/p>\n

Negyedszer, a f\u00e9nykem\u00e9nyed\u0151 gyanta (oligomer) gy\u00f3gy\u00edt\u00f3 zsugorod\u00e1sa.<\/p>\n

Az alacsony kikem\u00e9nyed\u00e9si zsugorod\u00e1s el\u0151seg\u00edti a kikem\u00e9ny\u00edtett f\u00f3lia tapad\u00e1s\u00e1nak javul\u00e1s\u00e1t a hordoz\u00f3hoz, az oligomer funkcionalit\u00e1s n\u0151, a t\u00e9rh\u00e1l\u00f3sod\u00e1si s\u0171r\u0171s\u00e9g n\u0151, a kikem\u00e9nyed\u00e9si zsugorod\u00e1s is n\u0151.<\/p>\n

\u00d6t\u00f6dsz\u00f6r, az oligomer \u00fcvegesed\u00e9si \u00e1tmeneti h\u0151m\u00e9rs\u00e9klete Tg.<\/p>\n

Oligomer Tg magas, \u00e1ltal\u00e1ban nagy kem\u00e9nys\u00e9g, j\u00f3 f\u00e9nyess\u00e9g; oligomer Tg alacsony, j\u00f3 rugalmass\u00e1g, \u00fct\u00e9s\u00e1ll\u00f3s\u00e1g vagy.<\/p>\n

Hatodik, toxicit\u00e1s \u00e9s irrit\u00e1ci\u00f3.<\/p>\n

Oligomer miatt a relat\u00edv molekulat\u00f6meg nagyobb, a legt\u00f6bb viszk\u00f3zus gyanta, nem ill\u00e9kony, nem gy\u00fal\u00e9kony \u00e9s robban\u00e1svesz\u00e9lyes elemek, a toxicit\u00e1s is alacsony, b\u0151rirrit\u00e1ci\u00f3 is alacsony.<\/p>\n

Ugyanazon sorozat term\u00e9kei<\/strong><\/h2>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
IBOMA<\/span><\/a><\/td>\nIzobornyl-metakril\u00e1t<\/td>\n7534-94-3<\/td>\n<\/tr>\n
CTFA<\/span><\/td>\n(5-etil-1,3-diox\u00e1n-5-il)metil-akril\u00e1t<\/td>\n66492-51-1<\/td>\n<\/tr>\n
IBOA<\/span><\/a><\/td>\nIzobornyil-akril\u00e1t<\/td>\n5888-33-5<\/td>\n<\/tr>\n
TPGDA<\/a><\/span><\/td>\nTripropil\u00e9n-glikol-diacril\u00e1t<\/td>\n42978-66-5<\/td>\n<\/tr>\n
PETA<\/a><\/span><\/td>\nPentaeritritol-trikril\u00e1t<\/td>\n3524-68-3<\/td>\n<\/tr>\n
TMPTMA<\/span><\/a><\/td>\nTrimetilolpropan-trimetakril\u00e1t<\/td>\n3290-92-4<\/td>\n<\/tr>\n
THFA<\/span><\/a><\/td>\nTetrahidrofurfuril-akril\u00e1t<\/td>\n2399-48-6<\/td>\n<\/tr>\n
NPGDA<\/a><\/span><\/td>\nNeopentil-glikol-diacril\u00e1t<\/td>\n2223-82-7<\/td>\n<\/tr>\n
TEGDA<\/span><\/td>\nTrietil\u00e9n-glikol-diacril\u00e1t<\/td>\n1680-21-3<\/td>\n<\/tr>\n
TMPTA<\/span><\/a><\/td>\nTrimetilolpropan-trikril\u00e1t<\/td>\n15625-89-5<\/td>\n<\/tr>\n
LMA<\/a><\/span><\/td>\nDodekil-metakril\u00e1t \/ Lauril-metakril\u00e1t<\/td>\n142-90-5<\/td>\n<\/tr>\n
TEGDMA<\/a><\/span><\/td>\nTrietil\u00e9nglikol-dimetakril\u00e1t<\/td>\n109-16-0<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

<\/h2>\n

L\u00e9pjen kapcsolatba vel\u00fcnk most!<\/b><\/strong><\/h2>\n

Ha COA, MSDS vagy TDS-re van sz\u00fcks\u00e9ge, k\u00e9rj\u00fck, t\u00f6ltse ki el\u00e9rhet\u0151s\u00e9g\u00e9t az al\u00e1bbi \u0171rlapon, \u00e1ltal\u00e1ban 24 \u00f3r\u00e1n bel\u00fcl felvessz\u00fck \u00d6nnel a kapcsolatot. \u00d6n is k\u00fcldhet nekem e-mailt info@longchangchemical.com<\/a><\/span> munkaid\u0151ben ( 8:30-18:00 UTC+8 H.-Szombat ) vagy haszn\u00e1lja a weboldal \u00e9l\u0151 chatj\u00e9t, hogy azonnali v\u00e1laszt kapjon.<\/b><\/strong><\/h4>","protected":false},"excerpt":{"rendered":"

Melyek az UV oligomerek kiv\u00e1laszt\u00e1s\u00e1nak elemei a f\u00e9nyre kem\u00e9nyed\u0151 bevonatformul\u00e1khoz? A f\u00e9nyre kem\u00e9nyed\u0151 bevonatokat UV-kem\u00e9nyed\u0151 bevonatoknak is nevezik, amelyek UV-f\u00e9nyt haszn\u00e1lnak energiaforr\u00e1sk\u00e9nt a bevonat kem\u00e9ny\u00edt\u00e9s\u00e9hez. Gyorsan, h\u0151 ig\u00e9nybev\u00e9tele n\u00e9lk\u00fcl kem\u00e9ny\u00edthet\u0151k olyan szubsztr\u00e1tokon, mint a pap\u00edr, m\u0171anyag, b\u0151r \u00e9s fa. A f\u00e9nykem\u00e9nyed\u0151 bevonatok [...]<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[114],"tags":[],"class_list":["post-5401","post","type-post","status-publish","format-standard","hentry","category-catalysts-chemical-auxiliary-agents"],"yoast_head":"\nWhat are the elements in selecting UV oligomers for light-curing coating formulations? - Longchang Chemical<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/longchangchemical.com\/hu\/what-are-the-elements-in-selecting-uv-oligomers-for-light-curing-coating-formulations\/\" \/>\n<meta property=\"og:locale\" content=\"hu_HU\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"What are the elements in selecting UV oligomers for light-curing coating formulations? - Longchang Chemical\" \/>\n<meta property=\"og:description\" content=\"What are the elements in selecting UV oligomers for light-curing coating formulations? 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