{"id":5331,"date":"2022-06-28T13:43:26","date_gmt":"2022-06-28T13:43:26","guid":{"rendered":"https:\/\/longchangchemical.com\/?p=5331"},"modified":"2022-07-06T11:37:34","modified_gmt":"2022-07-06T11:37:34","slug":"20-organic-reaction-mechanisms","status":"publish","type":"post","link":"https:\/\/longchangchemical.com\/hu\/20-organic-reaction-mechanisms\/","title":{"rendered":"20 szerves reakci\u00f3mechanizmus, amelyek meg\u00e9rt\u00e9se elengedhetetlen a szintetikus k\u00eds\u00e9rletekhez"},"content":{"rendered":"<h1><strong>20 szerves reakci\u00f3mechanizmus, amelyek meg\u00e9rt\u00e9se elengedhetetlen a szintetikus k\u00eds\u00e9rletekhez<\/strong><\/h1>\n<p>A Baeyer-Villiger-reakci\u00f3 mechanizmusa szerint a peressav el\u0151sz\u00f6r nukleofil add\u00edci\u00f3t hajt v\u00e9gre a karbonilcsoporton, majd a keton-karbonilcsoporton l\u00e9v\u0151 sz\u00e9nhidrog\u00e9ncsoport egy elektronp\u00e1rral \u00e1tv\u00e1ndorol a karbonil sz\u00e9natomhoz k\u00f6zvetlen\u00fcl kapcsol\u00f3d\u00f3 oxig\u00e9natomhoz a -O-O- csoportban, mik\u00f6zben O-O k\u00f6t\u00e9s heterol\u00edzis t\u00f6rt\u00e9nik. Ez teh\u00e1t egy \u00e1trendez\u0151d\u00e9si reakci\u00f3.<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-5332\" src=\"https:\/\/longchangchemical.com\/wp-content\/uploads\/2022\/06\/1.png\" alt=\"\" width=\"424\" height=\"145\" \/><\/p>\n<p>Egy optikailag akt\u00edv 3-fenilbut\u00e1non reakci\u00f3ja peressavval, ahol az \u00e1trendez\u0151d\u00e9si term\u00e9kek kir\u00e1lis sz\u00e9natomjainak bogy\u00f3i v\u00e1ltozatlanok maradnak, azt jelzi, hogy a reakci\u00f3 intramolekul\u00e1ris \u00e1trendez\u0151d\u00e9s.<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-5333\" src=\"https:\/\/longchangchemical.com\/wp-content\/uploads\/2022\/06\/2.png\" alt=\"\" width=\"344\" height=\"91\" \/><\/p>\n<p>Amikor egy aszimmetrikus keton oxid\u00e1l\u00f3dik, az \u00e1trendez\u0151d\u00e9si l\u00e9p\u00e9sben mindk\u00e9t csoport k\u00e9pes v\u00e1ndorolni, de m\u00e9g mindig van n\u00e9mi szelektivit\u00e1s, a v\u00e1ndorl\u00e1si k\u00e9pess\u00e9g\u00fck sorrendje a k\u00f6vetkez\u0151.<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-5334\" src=\"https:\/\/longchangchemical.com\/wp-content\/uploads\/2022\/06\/3.png\" alt=\"\" width=\"397\" height=\"42\" \/><\/p>\n<p>Az aldehid oxid\u00e1ci\u00f3j\u00e1nak mechanizmusa hasonl\u00f3, de a hidrog\u00e9n negat\u00edv ionok v\u00e1ndorl\u00e1sa a karbonsavhoz vezet.<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-5335\" src=\"https:\/\/longchangchemical.com\/wp-content\/uploads\/2022\/06\/4.png\" alt=\"\" width=\"196\" height=\"53\" \/><\/p>\n<p>&nbsp;<\/p>\n<h2><strong><b>L\u00e9pjen kapcsolatba vel\u00fcnk most!<\/b><\/strong><\/h2>\n<h4><strong><b>Ha <\/b><\/strong><strong><b>\u00c1rra vagy COA-ra, MSDS-re vagy TDS-re van sz\u00fcks\u00e9ge, k\u00e9rj\u00fck, forduljon hozz\u00e1nk. <\/b><\/strong><strong><b>t\u00f6ltse ki az al\u00e1bbi \u0171rlapot, \u00e9s jelezze, hogy \u00e1ltal\u00e1ban 24 \u00f3r\u00e1n bel\u00fcl felvessz\u00fck \u00d6nnel a kapcsolatot. \u00d6n is k\u00fcldhet nekem e-mailt <span style=\"color: #0000ff;\"><a style=\"color: #0000ff;\" href=\"mailto:info@longchangchemical.com\">info@longchangchemical.com<\/a><\/span> munkaid\u0151ben ( 8:30-18:00 UTC+8 H.-Szombat ) vagy haszn\u00e1lja a weboldal \u00e9l\u0151 chatj\u00e9t, hogy azonnali v\u00e1laszt kapjon.<\/b><\/strong><\/h4>","protected":false},"excerpt":{"rendered":"<p>20 szerves reakci\u00f3mechanizmus, amelyek meg\u00e9rt\u00e9se elengedhetetlen a szintetikus k\u00eds\u00e9rletekhez Baeyer-Villiger-reakci\u00f3 reakci\u00f3mechanizmusa A peressav el\u0151sz\u00f6r nukleofil add\u00edci\u00f3t hajt v\u00e9gre a karbonilcsoporton, majd a keton-karbonilcsoporton l\u00e9v\u0151 sz\u00e9nhidrog\u00e9ncsoport egy elektronp\u00e1rral a karbonil sz\u00e9natomhoz k\u00f6zvetlen\u00fcl kapcsol\u00f3d\u00f3 oxig\u00e9natomhoz v\u00e1ndorol a -O-O- [...]<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[114],"tags":[],"class_list":["post-5331","post","type-post","status-publish","format-standard","hentry","category-catalysts-chemical-auxiliary-agents"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.3.1 - 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